Tri-tert-butylstannane

Base Information

• Chemical Name: Tri-tert-butylstannane
• CAS No.: 16216-29-8
• Molecular Formula: C12H28Sn
• Molecular Weight: 291.064
• DSSTox Substance ID: DTXSID10776325
• Mol file: 16216-29-8.mol

Synonyms:t-bu3snh;Tri-tert-butylstannane;DTXSID10776325;16216-29-8

Chemical Property of Tri-tert-butylstannane

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 3
• Exact Mass: 291.113478
• Heavy Atom Count: 13
• Complexity: 128

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)(C)[Sn](C(C)(C)C)C(C)(C)C

Technology Process of Tri-tert-butylstannane

There total 1 articles about Tri-tert-butylstannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

({(CH3)3C}3Sn)2Hg (51241-76-0) + trimethylstannane (1631-73-8) → hexamethyldistannane (661-69-8) + tri-tert-butyltin hydride (16216-29-8)

Guidance literature:

In not given; byproducts: Hg; reaction for 30 min at 20°C;;

Reference yield: 98.0%

1-iodo-n-undecane (4282-44-4) + tri-tert-butyltin hydride (16216-29-8) → n-Undecane (1120-21-4) + tri-tert-butyltin iodide (30191-24-3)

Guidance literature:

With 2,2'-azobis(isobutyronitrile); In benzene; Refluxing in benzene (8 h, N2) after addn. of AIBN as a free radical initiator, quenching of react. mixt. by cooling in ice bath.; GLC anal. with n-dodecane as an added integration std.;

DOI:10.1021/om00100a021

Reference yield: 52.0%

bis(cycloocta-1,5-diene)platinum(0) (12130-66-4) + tri-tert-butyltin hydride (16216-29-8) + 1,3-bis-(2,6-diisopropylphenyl)-imidazol-2-ylidene (244187-81-3) → Pt(N,N’-bis-(2,6-(diisopropyl)phenyl)imidazol-2-ylidene)(SnBut3)(H)

Guidance literature:

bis(cycloocta-1,5-diene)platinum⁽⁰⁾; 1,3-bis-(2,6-diisopropylphenyl)-imidazol-2-ylidene; In hexane; at 20 ℃; for 0.75h; Glovebox; Inert atmosphere; Schlenk technique;

tri-tert-butyltin hydride; In hexane; for 1.16667h; Glovebox; Inert atmosphere; Schlenk technique;

DOI:10.1021/acs.inorgchem.6b00048

upstream raw materials:

({(CH₃)3C}3Sn)2Hg

trimethylstannane

Downstream raw materials:

1-hexene

methyl-cyclopentane

tri-tert-butyltin bromide

n-Undecane