Bis(3-biphenylyl)amine

Base Information

• Chemical Name: Bis(3-biphenylyl)amine
• CAS No.: 169224-65-1
• Molecular Formula: C24H19N
• Molecular Weight: 321.41400
• European Community (EC) Number: 834-071-1
• DSSTox Substance ID: DTXSID40597742
• Wikidata: Q82493380
• Mol file: 169224-65-1.mol

Synonyms:Bis(3-biphenylyl)amine;169224-65-1;Di([1,1'-biphenyl]-3-yl)amine;3-phenyl-N-(3-phenylphenyl)aniline;N,N-Bis(3-phenylphenyl)amine;Bis(3-Biphenyl)amine;3,3'-Iminobis(biphenyl);SCHEMBL3181560;DTXSID40597742;MFCD28129440;SB66522;AS-77764;DA-43548;B5048;T70405;N-([1,1'-Biphenyl]-3-yl)[1,1'-biphenyl]-3-amine;N-[1,1 inverted exclamation marka-Biphenyl]-3-yl[1,1 inverted exclamation marka-biphenyl]-3-amine

Chemical Property of Bis(3-biphenylyl)amine

Chemical Property:

• Melting Point: 90.0 to 94.0 °C
• Boiling Point: 518.5±39.0 °C(Predicted)
• PKA: 0.46±0.50(Predicted)
• PSA: 12.03000
• Density: 1.123±0.06 g/cm3(Predicted)
• LogP: 6.83720
• XLogP3: 6.7
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 4
• Exact Mass: 321.151749610
• Heavy Atom Count: 25
• Complexity: 344

Purity/Quality:

98%,99%, ^*data from raw suppliers

Bis(3-biphenylyl)amine ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C2=CC(=CC=C2)NC3=CC=CC(=C3)C4=CC=CC=C4

Technology Process of Bis(3-biphenylyl)amine

There total 1 articles about Bis(3-biphenylyl)amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

→ N-[1,1′-biphenyl]-3-yl[1,1′-biphenyl]-3-amine (169224-65-1)

Guidance literature:

With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; tri-tert-butyl phosphine; sodium t-butanolate; In toluene; at 90 ℃; for 3h; Inert atmosphere;

Reference yield: 89.4%

7-chlorobenzo[4,5]imidazo[1,2-f]phenanthridine (1228267-52-4) + N-[1,1′-biphenyl]-3-yl[1,1′-biphenyl]-3-amine (169224-65-1) → C43H29N3

Guidance literature:

With tri-tert-butyl phosphine; bis(dibenzylideneacetone)-palladium⁽⁰⁾; sodium t-butanolate; In toluene;

Reference yield: 81.0%

N-[1,1′-biphenyl]-3-yl[1,1′-biphenyl]-3-amine (169224-65-1) + 4,6-dibromodibenzo-[b,d]furan (201138-91-2) → C36H24BrNO

Guidance literature:

With palladium diacetate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; sodium t-butanolate; In toluene; at 110 ℃;

Refernces

• 1、 -. "COMPOUND FOR ORGANIC ELECTRONIC ELEMENT, ORGANIC ELECTRONIC ELEMENT USING THE SAME, AND AN ELECTRONIC DEVICE THEREOF". Paragraph 0252; 0274-0276; 0292; 0294; 0296; 0304. . Retrieved 2019/11/03.
• 2、 -. "COMPOUND FOR ORGANIC ELECTRONIC ELEMENT, ORGANIC ELECTRONIC ELEMENT USING THE SAME, AND AN ELECTRONIC DEVICE THEREOF". Paragraph 0250; 0272-0274; 0290; 0292; 0294; 0302. . Retrieved 2019/11/03.