methyl methyl(nitro)carbamate

Base Information

• Chemical Name: methyl methyl(nitro)carbamate
• CAS No.: 14442-54-7
• Molecular Formula: C3H6 N2 O4
• Molecular Weight: 134.092
• Mol file: 14442-54-7.mol

Synonyms:NSC 28521

Chemical Property of methyl methyl(nitro)carbamate

Chemical Property:

• Vapor Pressure: 0.842mmHg at 25°C
• Boiling Point: 181.7°Cat760mmHg
• Flash Point: 63.7°C
• Density: 1.32g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of methyl methyl(nitro)carbamate

There total 10 articles about methyl methyl(nitro)carbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

bis-(N-methyl-N-methoxycarbonylamino)methane (80552-92-7) → methyl-nitro-carbamic acid methyl ester (14442-54-7)

Guidance literature:

With nitronium tetrafluoborate; In acetonitrile; at 20 ℃; for 1h;

DOI:10.1007/BF00963423

Reference yield: 63.0%

acetyl-methyl-carbamic acid methyl ester (26407-93-2) → methyl-nitro-carbamic acid methyl ester (14442-54-7)

Guidance literature:

With nitronium tetrafluoborate; In acetonitrile; at 20 ℃; for 0.00833333h;

DOI:10.1007/BF00949493

Reference yield: 33.0%

N-methyl-N-carbomethoxymethanesulfamide (80368-94-1) → methyl-nitro-carbamic acid methyl ester (14442-54-7)

Guidance literature:

With nitronium tetrafluoborate; In acetonitrile; at 20 ℃; for 15h;

DOI:10.1007/BF00949493

upstream raw materials:

methyl N-methylcarbamate

acetyl-methyl-carbamic acid methyl ester

N-(carbomethoxy)-α-methoxydimethylamine

bis-(N-methyl-N-methoxycarbonylamino)methane

Downstream raw materials:

p-nitrophenyl methyl carbonate

methyl carbamate

methyl 1-methylhydrazine-1-carboxylate

methylnitroamine

Refernces

• 1、 Luk'yanov, O. A.,Mel'nikova, T. G.,Kashirskaya, E. G.,Tartakovskii, V. A.. "NITRATION OF N-CHLOROMETHYL-SUBSTITUTED SECONDARY AMIDES BY NITRONIUM TETRAFLUOROBORATE". . p. 1055 - 1057. Retrieved 2007/10/02.
• 2、 Luk'yanov, O. A.,Mel'nikova, T. G.,Tartakovskii, V. A.. "NITRATION OF ACYLATED SUBSTITUTED METHYLENEDIAMINES". . p. 1920 - 1923. Retrieved 2007/10/02.