Tetrabutylammonium nitrate, 97%

Base Information

• Chemical Name: Tetrabutylammonium nitrate, 97%
• CAS No.: 1941-27-1
• Molecular Formula: C₁₆H₃₆N*NO₃
• Molecular Weight: 304.473
• Hs Code.: 29239000
• NSC Number: 221165
• Mol file: 1941-27-1.mol

Synonyms:Tetrabutylammonium nitrate, 97%;NSC221165;1-Butanaminium,N,N-tributyl-, nitrate;NSC-221165;WLN: 4K4&4&4 &.N-O3;Tetrabutylammonium nitrate, purum, >=97.0% (NT)

Chemical Property of Tetrabutylammonium nitrate, 97%

Chemical Property:

• Appearance/Colour: white powder
• Melting Point: 116-118 °C(lit.)
• Refractive Index: 1.5500 (estimate)
• Boiling Point: 445.28°C (rough estimate)
• PSA: 68.88000
• Density: 0.9580 (rough estimate)
• LogP: 5.28770
• Sensitive.: Hygroscopic
• Solubility.: acetonitrile: 0.1 g/mL, clear, colorless
• Water Solubility.: <2 g/100 mL
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 12
• Exact Mass: 306.28824308
• Heavy Atom Count: 21
• Complexity: 142

Purity/Quality:

99.9% ^*data from raw suppliers

Tetrabutylammonium Nitrate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): O,Xi
• Hazard Codes: O,Xi
• Statements: 8-36/37/38-9
• Safety Statements: 17-26-37/39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CCCC[N+](CCCC)(CCCC)CCCC.[N+](=O)(O)O
• Uses: Tetra-n-butylammonium nitrate is used in coatings, printing ink, rubber, glass, leather and cosmetics. It serves as a supporting electrolyte in liquid ammonia. It is also used in the preparation of nitrates from triflates. It is employed in the inversion of configuration of alcohols through tosylates. It is also a source of NO3- used in nucleophilic substitution reactions. Further, it is used in the conversion of halides into ketones. In addition to this, it is used as a source of nitronium ions for the nitration of olefins, amides, ribonucleosides, glycols and aromatic compounds.

Technology Process of Tetrabutylammonium nitrate, 97%

There total 7 articles about Tetrabutylammonium nitrate, 97% which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

dinitrogen tetraoxide (10544-72-6) + tetrabutylammonium nitrite (26501-54-2) → tetrabutylammonium nitrate (1941-27-1)

Guidance literature:

In neat (no solvent); stirring (vacuum, 20°C, 30 min), nitrogen oxides evapn. (-10°C, vacuum); recrystn. (ethyl acetate); elem. anal.;

Reference yield: 96.0%

tetra-(n-butyl)ammonium iodide (311-28-4) → tetrabutylammonium nitrate (1941-27-1)

Guidance literature:

With trimethyl phosphite; nitric acid; at 0 - 60 ℃; for 15h; Inert atmosphere; neat (no solvent);

DOI:10.1002/ejoc.201200370

Reference yield: 95.0%

tetrabutylammomium bromide (1643-19-2) → tetrabutylammonium nitrate (1941-27-1)

Guidance literature:

With trimethyl phosphite; nitric acid; at 0 - 60 ℃; for 15h; Inert atmosphere; neat (no solvent);

DOI:10.1002/ejoc.201200370

upstream raw materials:

methanol

dinitrogen tetraoxide

tetrabutylammonium nitrite

tetra(n-butyl)ammonium hydroxide

Refernces

• 1、 Vasilchenko, Danila,Topchiyan, Polina,Berdyugin, Semen,Filatov, Evgeny,Tkachev, Sergey,Baidina, Iraida,Komarov, Vladislav,Slavinskaya, Elena,Stadnichenko, Andrey,Gerasimov, Evgeny. "Tetraalkylammonium Salts of Platinum Nitrato Complexes: Isolation, Structure, and Relevance to the Preparation of PtOx/CeO2 Catalysts for Lowerature CO Oxidation". . p. 6075 - 6087. Retrieved 2019/04/25.
• 2、 Jeon, Jong Yeob,Varghese, Jobi Kodiyan,Park, Ji Hae,Lee, Suck-Hyun,Lee, Bun Yeoul. "Efficient method for varying the anions in quaternary onium halides". experimental part. p. 3566 - 3569. Retrieved 2012/08/14.