Tris(1,3-dichloro-2-propyl)phosphate

Base Information

• Chemical Name: Tris(1,3-dichloro-2-propyl)phosphate
• CAS No.: 13674-87-8
• Deprecated CAS: 1425202-15-8
• Molecular Formula: C9H15Cl6O4P
• Molecular Weight: 430.907
• Hs Code.: HOSPHATE PRODUCT IDENTIFICATION
• European Community (EC) Number: 237-159-2
• UNII: B1PRV4G0T0
• DSSTox Substance ID: DTXSID9026261
• Nikkaji Number: J640H
• Wikipedia: Tris(1,3-dichloro-2-propyl)phosphate
• Wikidata: Q2454085
• ChEMBL ID: CHEMBL3182032
• Mol file: 13674-87-8.mol

Synonyms:Fyrol FR 2;TDCPP compound;tris(1,3-dichloro-2-propyl)phosphate

Chemical Property of Tris(1,3-dichloro-2-propyl)phosphate

Chemical Property:

• Appearance/Colour: colourless viscous liquid
• Vapor Pressure: 4.07E-08mmHg at 25°C
• Melting Point: -64 °C
• Refractive Index: n20/D 1.503
• Boiling Point: 457.4 °C at 760 mmHg
• Flash Point: 377.7 °C
• PSA: 54.57000
• Density: 1.487 g/cm³
• LogP: 4.68290
• Water Solubility.: <0.1 g/100 mL at 24℃
• XLogP3: 3.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 12
• Exact Mass: 429.880962
• Heavy Atom Count: 20
• Complexity: 243

Purity/Quality:

99% ^*data from raw suppliers

Tris(1,3-dichloro-2-propyl) Phosphate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn,N
• Hazard Codes: Xn,N
• Statements: 20/21/22-36/37/38-51/53-38-20-40
• Safety Statements: 26-36/37/39-61-36/37

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Other Classes -> Organophosphates, Other
• Canonical SMILES: C(C(CCl)OP(=O)(OC(CCl)CCl)OC(CCl)CCl)Cl
• Uses: Tris(1,3-dichloro-2-propyl) Phosphate is a flame retardant present in polyurethane foams. Tris(1,3-dichloro-2-propyl)phosphate [TDCPP] is a halogenated phosphorus flame retardant used in a variety of sectors, including manufacturing of paints/coatings, furniture and related products, building/construction materials, fabrics/textiles/leather products, and foam seating and bedding products (EPA, 2012). It is used extensively as an additive to flexible polyurethane foams (PUFs). Its end uses include molded automotive seating foam (e.g., seat cushions and headrests), slabstock foam in furniture, automotive fabric lining, and car roofing (ECHA, 2013). It is a high production volume chemical.

Technology Process of Tris(1,3-dichloro-2-propyl)phosphate

There total 3 articles about Tris(1,3-dichloro-2-propyl)phosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.8%

1,3-Dichloro-2-propanol (96-23-1) → CRP (13674-87-8)

Guidance literature:

With sulphate-doped anatase; trichlorophosphate; at 150 ℃; for 4h; Reagent/catalyst; Temperature;

Reference yield:

epichlorohydrin (106-89-8,24969-06-0,13403-37-7) → CRP (13674-87-8)

Guidance literature:

With hydrogenchloride; trichlorophosphate;

Reference yield:

→ CRP (13674-87-8)

Guidance literature:

Epichlorhydrin. POCl3;

upstream raw materials:

1,3-Dichloro-2-propanol

epichlorohydrin

Refernces

• 1、 -. "Preparation method of tris(1,3-dichloropropyl) phosphonate". Paragraph 0017; 0018; 0019; 0020; 0021; 0022. . Retrieved 2019/02/06.