Diphenyltin(2+);dichloride

Base Information

• Chemical Name: Diphenyltin(2+);dichloride
• CAS No.: 1135-99-5
• Molecular Formula: C12H10 Cl2 Sn
• Molecular Weight: 343.827
• Hs Code.: 2931900090
• Mol file: 1135-99-5.mol

Synonyms:diphenyltin(2+);dichloride;SCHEMBL151841

Chemical Property of Diphenyltin(2+);dichloride

Chemical Property:

• Appearance/Colour: white to off-white crystalline powder
• Vapor Pressure: 0.000315mmHg at 25°C
• Melting Point: 41-43 °C(lit.)
• Boiling Point: 330.7 °C at 760 mmHg
• Flash Point: 153.8 °C
• PSA: 0.00000
• Density: g/cm³
• LogP: 2.72060
• Sensitive.: Moisture Sensitive
• Solubility.: Sparingly Soluble (2.4E-3 g/L) (25°C), Calc.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 343.918158
• Heavy Atom Count: 15
• Complexity: 116

Purity/Quality:

98%,99%, ^*data from raw suppliers

Diphenyltin dichloride ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn
• Hazard Codes: Xn
• Statements: 20/21/22-36/37/38
• Safety Statements: 26-37/39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1=CC=C(C=C1)[Sn+2]C2=CC=CC=C2.[Cl-].[Cl-]
• Uses: Used in the manufacture of chemicals.

Technology Process of Diphenyltin(2+);dichloride

There total 57 articles about Diphenyltin(2+);dichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tetraphenyltin(IV) (595-90-4) + boron trichloride (10294-34-5) → diphenylboronchloride (3677-81-4) + diphenyltin(IV) dichloride (1135-99-5)

Guidance literature:

Reference yield:

tin(IV) chloride (7646-78-8) + triphenylbismuthane (603-33-8) → bismuth(III) chloride (7787-60-2) + diphenyltin(IV) dichloride (1135-99-5)

Guidance literature:

In benzene;

DOI:10.1039/CT9242500864

Reference yield:

3,4-dimethyl-1,1-diphenyl-1-stannylcyclopent-3-ene (1147101-06-1) + dimethyltin dichloride (753-73-1) → 2-chloro-2,2,4,4-tetramethyl-1-oxa-3-chlora-2,4-distannacyclobutane dimer (85990-37-0) + C14H16Cl2Sn2 + diphenyltin(IV) dichloride (1135-99-5) + 2,3-dimethyl-buta-1,3-diene (513-81-5)

Guidance literature:

With oxygen; In Cyclohexane-d12; Photolysis;

DOI:10.1021/acs.organomet.5b00615

upstream raw materials:

diphenyl-di-n-propyltin(IV)

[1]naphthyl-triphenyl stannane

Iodine monochloride

di-[1]naphthyl-diphenyl stannane

Downstream raw materials:

biphenyl

1-Nitro-2-phenyl-2-(2-thienyl)ethane

2-nitro-1-(m-nitrophenyl)-1-phenylethane

tin

Refernces

• 1、 Kuivila, H. G.,Sawyer, A. K.,Armour, A. G.. "". . p. 1426 - 1429. Retrieved 1961.
• 2、 Goddard, D.,Goddard, A. E.. "". . p. 256 - 261. Retrieved 1922.
• 3、 Bock, Rudolf,Niederauer, Heinz-Theo,Behrends, Karl. "-". . p. 33 - 47. Retrieved 1962.
• 4、 Cabon, Yves,Gebbink, Robertus J. M. Klein,Deelman, Berth-Jan. "Palladium-catalyzed dehydrostannylation of n-alkyltin trichlorides". . p. 8651 - 8655. Retrieved 2011/10/10.
• 5、 Portnyagin, Ivan A.,Lunin, Valery V.,Nechaev, Mikhail S.. "Reverse Kocheshkov reaction - Redistribution reactions between RSn(OCH2CH2NMe2)2Cl (R = Alk, Ar) and PhSnCl3: Experimental and DFT study". . p. 3847 - 3850. Retrieved 2009/04/06.