Dodec-11-en-1-al

Base Information

• Chemical Name: Dodec-11-en-1-al
• CAS No.: 51148-68-6
• Molecular Formula: C12H22 O
• Molecular Weight: 182.306
• Hs Code.: 2912190090
• European Community (EC) Number: 257-016-8
• DSSTox Substance ID: DTXSID50199170
• Nikkaji Number: J1.694.096H
• Wikidata: Q83072079
• Mol file: 51148-68-6.mol

Synonyms:Dodec-11-en-1-al;11-Dodecenal;51148-68-6;EINECS 257-016-8;dodec-11-enal;SCHEMBL1701705;DTXSID50199170;LRLMEXPRIMROMY-UHFFFAOYSA-N;AKOS006324991

Chemical Property of Dodec-11-en-1-al

Chemical Property:

• Vapor Pressure: 0.0211mmHg at 25°C
• Boiling Point: 250.9°Cat760mmHg
• Flash Point: 105.1°C
• PSA: 17.07000
• Density: 0.832g/cm³
• LogP: 3.88220
• XLogP3: 4.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 10
• Exact Mass: 182.167065321
• Heavy Atom Count: 13
• Complexity: 118

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=CCCCCCCCCCC=O

Technology Process of Dodec-11-en-1-al

There total 13 articles about Dodec-11-en-1-al which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

11-dodecenenittrile (5048-44-2) → dodec-11-enal (51148-68-6)

Guidance literature:

With diisobutylaluminium hydride; In hexane; toluene; 1.) 0 deg C, 3 h, 2.) 10 deg C, 1 h;

DOI:10.1021/jo00079a024

Reference yield: 76.0%

1-undecen-11-ylbromide (7766-50-9) + N,N-dimethyl-formamide (68-12-2,33513-42-7) → dodec-11-enal (51148-68-6)

Guidance literature:

1-undecen-11-ylbromide; With magnesium; ethylene dibromide; In tetrahydrofuran; for 2h; Inert atmosphere;

N,N-dimethyl-formamide; In tetrahydrofuran; at 0 - 20 ℃; for 0.333333h; Inert atmosphere;

DOI:10.1021/jo5000829

Reference yield: 64.0%

10-undecen-1-ylmagnesium bromide (88476-93-1) + N,N-dimethyl-formamide (68-12-2,33513-42-7) → dodec-11-enal (51148-68-6)

Guidance literature:

In tetrahydrofuran; for 2h; Ambient temperature;

DOI:10.1007/BF00630186

upstream raw materials:

12-hydroxydodecan-2-one

11-dodecenenittrile

10-undecen-1-ylmagnesium bromide

N,N-dimethyl-formamide

Downstream raw materials:

(E)-tetradec-11-en-1-yl acetate

(E)-11-tetradecen-1-ol

E,Z-11-tetradecen-1-al

1-tosyloxytetradeca-3E,13-diene

Refernces

• 1、 Chung, Won-Jin,Carlson, Joseph S.,Vanderwal, Christopher D.. "General approach to the synthesis of the chlorosulfolipids danicalipin A, mytilipin A, and malhamensilipin A in enantioenriched form". . p. 2226 - 2241. Retrieved 2014/04/03.
• 2、 Font, Rafael,Aracil, Ignacio,Fullana, Andrés,Conesa, Juan A.. "Semivolatile and volatile compounds in combustion of polyethylene". . p. 615 - 627. Retrieved 2007/10/03.