Decylsuccinic anhydride

Base Information

• Chemical Name: Decylsuccinic anhydride
• CAS No.: 18470-76-3
• Molecular Formula: C14H24 O3
• Molecular Weight: 240.343
• Hs Code.: 2917190090
• European Community (EC) Number: 242-350-9
• NSC Number: 80684
• DSSTox Substance ID: DTXSID701307832
• Nikkaji Number: J49.506I
• Mol file: 18470-76-3.mol

Synonyms:Decylsuccinic anhydride;18470-76-3;N-Decylsuccinic anhydride;3-decyloxolane-2,5-dione;3-Decyldihydrofuran-2,5-dione;Succinic anhydride, decyl-;2,5-Furandione, 3-decyldihydro-;EINECS 242-350-9;NSC 80684;BRN 0168302;2,5-Flurandione, 3-decyldihydro-;4-17-00-05889 (Beilstein Handbook Reference);MFCD00014548;2, 3-decyldihydro-;n-decyl succinic anhydride;WLN: T5VOVTJ D10;SCHEMBL351953;N-DECYLSUCCINICANHYDRIDE;3-Decyldihydro-2,5-furandione;3-Decyldihydro-2,5-furandione #;DTXSID701307832;NSC80684;NSC-80684;2,5-Flurandione, 3-decyldihydro- (9CI);LS-147508;CS-0449234;D0036;FT-0726347;D89585

Chemical Property of Decylsuccinic anhydride

Chemical Property:

• Vapor Pressure: 2.39E-05mmHg at 25°C
• Melting Point: 69 °C
• Refractive Index: 1.5800 (estimate)
• Boiling Point: 359.3°Cat760mmHg
• Flash Point: 160.7°C
• PSA: 43.37000
• Density: 0.991g/cm³
• LogP: 3.60690
• XLogP3: 4.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 9
• Exact Mass: 240.17254462
• Heavy Atom Count: 17
• Complexity: 248

Purity/Quality:

98%,99%, ^*data from raw suppliers

Decylsuccinic Anhydride ^*data from reagent suppliers

Safty Information:

• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCCCCCC1CC(=O)OC1=O

Technology Process of Decylsuccinic anhydride

There total 6 articles about Decylsuccinic anhydride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

carbon monoxide (201230-82-2) + β-tridecanolactone (51758-19-1) → 3-decyldihydrofuran-2,5-dione (18470-76-3)

Guidance literature:

With ({1,2-di[(2-OH-3,5-di-tBu)PhCH=N]Ph}Al[THF]2)⁺[Co(CO)4]^-; In toluene; at 80 ℃; for 24h; under 10343 Torr;

DOI:10.1021/ja048946m

Reference yield: 99.0%

→ 3-decyldihydrofuran-2,5-dione (18470-76-3)

Guidance literature:

With [(tetra(4-chlorophenyl)porphyrinato)aluminium(III)bis(tetrahydrofuran)][tetracarbonylcobaltate]; In 1,4-dioxane; at 90 ℃; for 3h; under 43958.7 Torr;

Reference yield:

Decyl-oxiran (2855-19-8) + carbon monoxide (201230-82-2) → 3-decyldihydrofuran-2,5-dione (18470-76-3)

Guidance literature:

[(meso-tetra(4-Cl-C₆H₄)porphyrinato)Al(THF)2]+[Co(CO)4]-; In 1,4-dioxane; at 90 ℃; for 3h; under 43958.7 Torr;

DOI:10.1021/ja066901a

upstream raw materials:

dodecane-1,1,2-tricarboxylic acid

carbon monoxide

β-tridecanolactone

Decyl-oxiran

Downstream raw materials:

Decylsuccinic acid

decylbutanediperoxoic acid

2-Phenylcarbamoylmethyl-dodecanoic acid

2-[(4-Methoxy-phenylcarbamoyl)-methyl]-dodecanoic acid

Refernces

• 1、 Rowley, John M.,Lobkovsky, Emil B.,Coates, Geoffrey W.. "Catalytic double carbonylation of epoxides to succinic anhydrides: Catalyst discovery, reaction scope, and mechanism". . p. 4948 - 4960. Retrieved 2008/02/03.
• 2、 Nargund,Prasad,Thakur. "Potential antitubercular drugs: II. Synthesis of some mono-N-arylamides of alkylsuccinic acids". . p. 479 - 482. Retrieved 2007/10/08.