Didecyl maleate

Base Information

• Chemical Name: Didecyl maleate
• CAS No.: 45298-06-4
• Molecular Formula: C24H44 O4
• Molecular Weight: 396.611
• Hs Code.: 2917190090
• European Community (EC) Number: 256-226-7
• NSC Number: 6736
• DSSTox Substance ID: DTXSID101303268
• Nikkaji Number: J114.864H
• Wikidata: Q76304755
• Mol file: 45298-06-4.mol

Synonyms:Didecyl maleate;Maleic acid, didecyl ester;didecyl (Z)-but-2-enedioate;45298-06-4;EINECS 256-226-7;2-Butenedioic acid (Z)-, didecyl ester;AI3-22479;2-Butenedioic acid, (Z)-, didecyl ester;Maleic acid didecyl ester;SCHEMBL629797;NSC6736;DTXSID101303268;NSC-6736;1,4-Didecyl (2Z)-2-butenedioate;LS-88645

Chemical Property of Didecyl maleate

Chemical Property:

• Vapor Pressure: 4.54E-09mmHg at 25°C
• Refractive Index: 1.4521 (25℃)
• Boiling Point: 471.7°Cat760mmHg
• Flash Point: 221.3°C
• PSA: 52.60000
• Density: 0.932g/cm³
• LogP: 6.91040
• XLogP3: 9.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 22
• Exact Mass: 396.32395988
• Heavy Atom Count: 28
• Complexity: 354

Purity/Quality:

98%Min ^*data from raw suppliers

DIDECYL MALEATE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCCCCCOC(=O)C=CC(=O)OCCCCCCCCCC
• Isomeric SMILES: CCCCCCCCCCOC(=O)/C=C\C(=O)OCCCCCCCCCC

Technology Process of Didecyl maleate

There total 6 articles about Didecyl maleate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

maleic anhydride (108-31-6) + 1-Decanol (112-30-1) → didecyl maleate (45298-06-4)

Guidance literature:

With sulfuric acid; In benzene; at 110 ℃;

DOI:10.1016/j.tet.2005.04.037

Reference yield: 54.0%

1-Decanol (112-30-1) + (3-decyloxycarbonyl)acrylic acid (364745-47-1) → di-n-decyl fumarate (6290-56-8,45298-06-4,16669-28-6)

Guidance literature:

With dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; In dichloromethane; at 20 ℃; for 24h; under 760.051 Torr; Inert atmosphere;

DOI:10.1021/acs.joc.6b00526

Reference yield:

maleic anhydride (108-31-6) + 1-bromo dodecane (112-29-8) → didecyl maleate (45298-06-4)

Guidance literature:

With sulfuric acid; In toluene; Heating;

DOI:10.1246/bcsj.51.1877

upstream raw materials:

maleic anhydride

1-bromo dodecane

1-Decanol

fumaryl dichloride

Downstream raw materials:

didecyl 2-(tosylamino)succinate

sodium 1,2-bis(decyloxycarbonyl)ethanesulfonate

sodium di-n-decyl sulfosuccinate

di(decyloxy)sulfosuccinic acid

Refernces

• 1、 Matsumoto, Jin,Ishizu, Masayuki,Kawano, Ryu-Ichiro,Hesaka, Daisuke,Shiragami, Tsutomu,Hayashi, Yoshimi,Yamashita, Toshiaki,Yasuda, Masahide. "Generation of quinone methide from aminomethyl(hydroxy)arenes precursors in aqueous solution". . p. 5735 - 5740. Retrieved 2007/10/03.