Molybdenum phosphide

Base Information

• Chemical Name: Molybdenum phosphide
• CAS No.: 12163-69-8
• Deprecated CAS: 12136-79-7,1604843-06-2,1852543-93-1
• Molecular Formula: MoP
• Molecular Weight: 126.914
• European Community (EC) Number: 235-312-8
• Wikidata: Q4492129
• Mol file: 12163-69-8.mol

Synonyms:Molybdenum phosphide;12163-69-8;phosphanylidynemolybdenum;Molybdenum phosphide (MoP);EINECS 235-312-8;Mo-P;MFCD00049982;Q4492129

Chemical Property of Molybdenum phosphide

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: 0.86120
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 128.879166
• Heavy Atom Count: 2
• Complexity: 10

Purity/Quality:

98%Min ^*data from raw suppliers

Molybdenum phosphide 99.5% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: P#[Mo]

Technology Process of Molybdenum phosphide

There total 35 articles about Molybdenum phosphide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

diammonium hydrogenphosphate + hexaammonium heptamolybdate tetrahydrate → molybdenum phosphide (12163-69-8) + molybdenum(VI) oxide + molybdenum (7439-98-7)

Guidance literature:

With H₂; In neat (no solvent); pors of γ-Al2O3 filled with 1:1 aq. soln. of paramolybdate and hydrogenphosphate, heated in quartz reactor by temperature-programmed reduction with H2 from 300 to 1200 K; cooled to room temp., detected by XRD;

DOI:10.1016/S0021-9517(03)00086-1

Reference yield:

sodium hypophosphite (10039-56-2) + molybdenum(VI) oxide → molybdenum phosphide (12163-69-8)

Guidance literature:

In H₂O; byproducts: P, H2O; thermal decompn. of oxide and NaH2PO2; stoich. amt. of NaH2PO2 dissolvedin deionized H2O, then oxide added, the slurry evapd. slowly to dehydra te; dried (80°C, 8h), heated (400°C, 0.5 h in static Ar), washed (deionized H2O, 3 times), dried (120°C, 3 h); XRD;

DOI:10.1016/j.jcat.2010.02.031

Reference yield:

molybdenum (IV) sulfide + sodium hypophosphite (10039-56-2) → molybdenum phosphide (12163-69-8)

Guidance literature:

at 450 ℃; for 3h; Inert atmosphere;

DOI:10.1039/c9ta00404a

upstream raw materials:

phosphan

molybdenum

water

phosphoric acid

Refernces

• 1、 Li, Xiuying,Huang, Shuangqiu,Xu, Huaihao,Deng, Yuepeng,Wang, Zhu,Liu, Zhao-Qing. "Molybdenum phosphide (MoP) with dual active sites for the degradation of diclofenac in Fenton-like system". . p. 1321 - 1324. Retrieved 2022.
• 2、 Zhang, Yifan,Park, Soo-Jin. "Phosphorization-derived MoP@MoO3-x nanowires for selective photocatalytic oxidation of benzyl alcohol to benzaldehyde". . p. 332 - 341. Retrieved 2021.
• 3、 Rodriguez, Jose A.,Kim, Jae-Yong,Hanson, Jonathan C.,Sawhill, Stephanie J.,Bussell, Mark E.. "Physical and chemical properties of MoP, Ni2P, and MoNiP hydrodesulfurization catalysts: Time-resolved X-ray diffraction, density functional, and hydrodesulfurization activity studies". . p. 6276 - 6285. Retrieved 2003.
• 4、 Phillips, Diana C.,Sawhill, Stephanie J.,Self, Randy,Bussell, Mark E.. "Synthesis, characterization, and hydrodesulfurization properties of silica-supported molybdenum phosphide catalysts". . p. 266 - 273. Retrieved 2002.
• 5、 Yao, Zhiwei,Li, Meng,Wang, Xiang,Qiao, Xue,Zhu, Jiang,Zhao, Yu,Wang, Guanzhang,Yin, Jingzhou,Wang, Haiyan. "A novel synthetic route to transition metal phosphide nanoparticles". . p. 5503 - 5509. Retrieved 2015.
• 6、 Cheng, Ruihua,Shu, Yuying,Zheng, Mingyuan,Li, Lin,Sun, Jun,Wang, Xiaodong,Zhang, Tao. "Molybdenum phosphide, a new hydrazine decomposition catalyst: Microcalorimetry and FTIR studies". . p. 397 - 400. Retrieved 2007.
• 7、 Teng, Yang,Wang, Anjie,Li, Xiang,Xie, Jianguo,Wang, Yao,Hu, Yongkang. "Preparation of high-performance MoP hydrodesulfurization catalysts via a sulfidation-reduction procedure". . p. 369 - 379. Retrieved 2009.
• 8、 Yang, Jian,Zhang, Fengjun,Wang, Xin,He, Dongsheng,Wu, Geng,Yang, Qinghua,Hong, Xun,Wu, Yuen,Li, Yadong. "Porous Molybdenum Phosphide Nano-Octahedrons Derived from Confined Phosphorization in UIO-66 for Efficient Hydrogen Evolution". . p. 12854 - 12858. Retrieved 2016.
• 9、 Clark, Paul A.,Oyama, S. Ted. "Alumina-supported molybdenum phosphide hydroprocessing catalysts". . p. 78 - 87. Retrieved 2003.
• 10、 Weng, Baicheng,Wang, Xiaoming,Grice, Corey R.,Xu, Fenghua,Yan, Yanfa. "A new metal-organic open framework enabling facile synthesis of carbon encapsulated transition metal phosphide/sulfide nanoparticle electrocatalysts". . p. 7168 - 7178. Retrieved 2019.