N-(2-aminoethyl)ethane-1,2-diamine hydrochloride (1:1)

Base Information

• Chemical Name: N-(2-aminoethyl)ethane-1,2-diamine hydrochloride (1:1)
• CAS No.: 21120-99-0
• Molecular Formula: C₄H₁₆N₃*3Cl
• Molecular Weight: 212.55
• Mol file: 21120-99-0.mol

Synonyms:

Chemical Property of N-(2-aminoethyl)ethane-1,2-diamine hydrochloride (1:1)

Chemical Property:

• Vapor Pressure: 0.0241mmHg at 25°C

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of N-(2-aminoethyl)ethane-1,2-diamine hydrochloride (1:1)

There total 1 articles about N-(2-aminoethyl)ethane-1,2-diamine hydrochloride (1:1) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

3-azapentane-1,5-diamine (111-40-0,98824-35-2) → diethylenetriamine dihydrochloride (3488-89-9,3488-90-2,4109-20-0,21120-99-0,71196-21-9)

Guidance literature:

With hydrogenchloride; at 0 ℃;

DOI:10.1021/ja00337a050

Reference yield: 93.0%

sodium hexachloroplatinate + sodium hexachloroiridate + nitric acid (7697-37-2,78989-43-2) + diethylenetriamine dihydrochloride (3488-89-9,3488-90-2,4109-20-0,21120-99-0,71196-21-9) → NH2(CH2CH2NH3)2(3+)*0.5PtCl6(2-)*0.5IrCl6(2-)*NO3(1-)=(NH2(C2H4NH3)2)[Pt0.5Ir0.5Cl6](NO3)

Guidance literature:

In hydrogenchloride; nitric acid; aq. HNO3; soln. of triamine*3HCl in 1M HNO3 added in portions to soln. of complex salts in 1 M HCl contg. concd. HNO3 at ca. 0°C under stirring, mixt. stored at 0°C (ice bath) for 20 min; ppt. filtered off, washed with cold ethanol and ether, dried in air; elem. anal.;

DOI:10.1134/S1070328407010071

Reference yield: 70.0%

gold(III) chloride trihydrate + diethylenetriamine dihydrochloride (3488-89-9,3488-90-2,4109-20-0,21120-99-0,71196-21-9) → [Au-chloro-bis(2-aminoethyl)amine]Cl2

Guidance literature:

With NaOH; In water; aq. soln. of amine added to aq. soln. of HAuCl4, pptd., aq. NaOH added,stirred at 0°C for 2 h; filtered, washed with cold EtOH, dried over P2O5, elem. anal.;

DOI:10.1039/DT9800000220

upstream raw materials:

3-azapentane-1,5-diamine

Downstream raw materials:

1,2,6-(mer)-Rh(dien)Cl₃

1,2,3-(fac)-Rh(dien)Cl₃

Refernces

• 1、 Sigel, Helmut,Hofstetter, Fritz,Martin Bruce R.,Milburn, Ronald M.,Scheller-Krattiger, Verena,Scheller, Kurt H.. "General Considerations on Transphosphorylations: Mechanism of the Metal Ion Facilitated Dephosphorylation of Nucleoside 5'-Triphosphates, Including Promotion of ATP Dephosphorilation by Addition of Adenosine 5'-Monophosphate". . p. 7935 - 7946. Retrieved 2007/10/02.