Sulfur fluoride (SF5), (SP-5-11)-

Base Information

• Chemical Name: Sulfur fluoride (SF5), (SP-5-11)-
• CAS No.: 10546-01-7
• Molecular Formula: F5S
• Molecular Weight: 127.058
• DSSTox Substance ID: DTXSID601299492
• Mol file: 10546-01-7.mol

Synonyms:DTXSID601299492;Sulfur fluoride (SF5), (SP-5-11)-

Chemical Property of Sulfur fluoride (SF5), (SP-5-11)-

Chemical Property:

• Vapor Pressure: 922mmHg at 25°C
• Boiling Point: 19.5°Cat760mmHg
• Flash Point: °C
• PSA: 38.80000
• Density: g/cm³
• LogP: 2.48150
• XLogP3: 3.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 0
• Exact Mass: 126.96408698
• Heavy Atom Count: 6
• Complexity: 37.1

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: F[S](F)(F)(F)F

Technology Process of Sulfur fluoride (SF5), (SP-5-11)-

There total 5 articles about Sulfur fluoride (SF5), (SP-5-11)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

pentafluorosulfanyl bromide (15607-89-3) + hydrogen → sulfurpentafluoride (10546-01-7) + hydrogen bromide (10035-10-6,12258-64-9)

Guidance literature:

In gaseous matrix; reaction of H (produced on microwave discharge) and SF5Br in Ar; not isolated; Kinetics;

DOI:10.1063/1.440043

Reference yield:

sulfur(VI) hexafluoride (2551-62-4) → sulfurpentafluoride (10546-01-7) + sulfur tetrafluoride (7783-60-0) + fluorine

Guidance literature:

In gas; other Radiation; pulses of 800 keV electrons; not isolated, reaction followed by transient UV-absorption of CH3 produced by reacting F with CH4;

DOI:10.1016/0009-2614(95)00154-V

Reference yield:

sulfur(VI) hexafluoride (2551-62-4) + aluminium (7429-90-5) → sulfurpentafluoride (10546-01-7) + aluminium fluoride (13595-82-9)

Guidance literature:

In neat (no solvent, gas phase); between 499 and 813 K; not isolated, detected by laser-induced fluorescence; Kinetics;

DOI:10.1021/jp012895n

upstream raw materials:

pentafluorosulfanyl bromide

krypton ⁽¹⁺⁾

sulfur(VI) hexafluoride

aluminium

Downstream raw materials:

sulfur tetrafluoride

hydrogen fluoride

Refernces

• 1、 Fagerstroem, Kjell,Jodkowski, Jerzy T.,Lund, Anders,Ratajczak, Emil. "". . . Retrieved 1995.
• 2、 Parker, James K.,Garland, Nancy L.,Nelson. "Kinetics of the reaction Al + SF6 in the temperature range 499-813 K". . p. 307 - 311. Retrieved 2002.
• 3、 Malins, R. J.,Setser, D. W.. "Rate constants and vibrational energy disposal for reaction of H atoms with Br2, SF5Br, PBr3, SF5, and SF4". . p. 5666 - 5680. Retrieved 2007/10/02.