9-Octadecenedioic acid, dimethyl ester, (9E)-

Base Information

• Chemical Name: 9-Octadecenedioic acid, dimethyl ester, (9E)-
• CAS No.: 24753-49-9
• Molecular Formula: C20H36O4
• Molecular Weight: 340.503
• Mol file: 24753-49-9.mol

Synonyms:

Chemical Property of 9-Octadecenedioic acid, dimethyl ester, (9E)-

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 9-Octadecenedioic acid, dimethyl ester, (9E)-

There total 93 articles about 9-Octadecenedioic acid, dimethyl ester, (9E)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 42.7%

Methyl oleate (112-62-9) → trans-9-octadecene (7206-25-9) + Dimethyl (E)-octadec-9-enedioate (24753-49-9)

Guidance literature:

With tungsten(VI) oxychloride; dimethyltitanocene; In benzene; at 70 ℃; for 10h;

DOI:10.1016/S0022-328X(00)80988-2

Reference yield: 25.0%

methyl (9E)-octadec-9-enoate (2462-84-2) → trans-9-octadecene (7206-25-9) + Dimethyl (E)-octadec-9-enedioate (24753-49-9)

Guidance literature:

With tetradecane; C₄₃H₄₄Cl₂N₂ORuS₂; In tetrahydrofuran; for 24h; Reagent/catalyst; Inert atmosphere; Glovebox; Sealed tube;

DOI:10.1021/acs.organomet.7b00555

Reference yield:

Methyl oleate (112-62-9) → trans-9-octadecene (7206-25-9) + octadeca-9Z-ene (1779-13-1) + Dimethyl (E)-octadec-9-enedioate (24753-49-9)

Guidance literature:

In hexane; at 45 ℃; for 5h; Inert atmosphere;

DOI:10.1016/j.apcata.2013.01.026

upstream raw materials:

cis-16-bromo-9-hexadecenoic acid methyl ester

sodium diethylmalonate

Methyl oleate

9-octadecyne-1,18-dioic acid dimethyl ester

Downstream raw materials:

(9Z)-octadec-9-enedioic acid

(Z)-Octadec-9-enedioic acid bis-{2-[2-(2-{2-[2-(2-hydroxy-ethoxy)-ethoxy]-ethoxy}-ethoxy)-ethoxy]-ethyl} ester

methyl 9-decenoate

methyl 10-cyano-dec-9-enoate

Refernces

• 1、 -. "TUNGSTEN IMIDO ALKYLIDENE O-BITET AND O-BINOL COMPLEXES AND USE THEREOF IN OLEFIN METATHESIS REACTIONS". Paragraph 00222-00224. . Retrieved 2020/12/11.
• 2、 Müller, Daniel S.,Raoul, Yann,Le N?tre, Jér?me,Baslé, Olivier,Mauduit, Marc. "In Situ Generation of Ru-Based Metathesis Catalyst. A Systematic Study". . p. 3511 - 3518. Retrieved 2019/04/01.