Cyclohexanone, 4-ethylidene-

Base Information

• Chemical Name: Cyclohexanone, 4-ethylidene-
• CAS No.: 26682-82-6
• Molecular Formula: C8H12O
• Molecular Weight: 124.183
• Mol file: 26682-82-6.mol

Synonyms:

Chemical Property of Cyclohexanone, 4-ethylidene-

Chemical Property:

Purity/Quality:

95+% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Cyclohexanone, 4-ethylidene-

There total 5 articles about Cyclohexanone, 4-ethylidene- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

4-ethylidenecyclohexanone ethylene acetal (137182-68-4) → 4-ethylidenecyclohexan-1-one (26682-82-6)

Guidance literature:

With sulfuric acid; silica gel; In dichloromethane; water; at 20 ℃; for 2h;

DOI:10.1002/adsc.201200759

Reference yield:

cyclohexanedione monoethylene ketal (4746-97-8) → 4-ethylidenecyclohexan-1-one (26682-82-6)

Guidance literature:

Multi-step reaction with 2 steps

1: tetrahydrofuran; hexane / 24 h / Ambient temperature

2: 14.7 g / silica gel, 20percent aq. H₂SO₄ / CH₂Cl₂ / 2 h / Ambient temperature

With sulfuric acid; silica gel; In tetrahydrofuran; hexane; dichloromethane;

DOI:10.1080/00397919108019807

Reference yield:

3-vinyl-pentane-1,3,5-tricarboxylic acid → 4-ethylidenecyclohexan-1-one (26682-82-6)

Guidance literature:

With barium carbonate;

upstream raw materials:

4-ethylidenecyclohexanone ethylene acetal

cyclohexanedione monoethylene ketal

3-vinylpentane-1,3,5-trinitrile

Downstream raw materials:

4-ethylcyclohexanone diethyl acetal

(E)-4-ethylidene-ε-caprolactone

C₂₃H₂₈F₆N₂O

C₂₆H₃₆F₃N₃O*ClH

Refernces

• 1、 -. "Spiro compounds or salts thereof and preventives/remedies for autoimmune diseases and AP-1 inhibitors containing the same". . . Retrieved 2008/06/13.