Tetradecane, 7,8-dimethyl-

Base Information

• Chemical Name: Tetradecane, 7,8-dimethyl-
• CAS No.: 2801-86-7
• Molecular Formula: C16H34
• Molecular Weight: 226.446
• Mol file: 2801-86-7.mol

Synonyms:Tetradecane,7,8-dimethyl;7,8-Dimethyl-tetradecan;7,8-dimethyl-tetradecane;

Chemical Property of Tetradecane, 7,8-dimethyl-

Chemical Property:

• PSA: 0.00000
• LogP: 6.19940

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Tetradecane, 7,8-dimethyl-

There total 12 articles about Tetradecane, 7,8-dimethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 24.0%

2-iodooctane (36049-78-2,557-36-8) → octane (111-65-9) + cis-2-octene (7642-04-8) + trans-2-Octene (13389-42-9) + oct-1-ene (111-66-0,25068-25-1) + 7,8-Dimethyltetradecane (2801-86-7) + di-sec-octylmercury (82294-07-3)

Guidance literature:

With tetramethylammonium perchlorate; In N,N-dimethyl-formamide; Product distribution; Mechanism; Ambient temperature; electrochemical reduction at mercury; different supporting electrolyte; different proton donors; other halogen 2-substituted octane;

DOI:10.1021/jo00139a003

Reference yield: 10.0%

2-bromooctane (557-35-7,60251-57-2) → octane (111-65-9) + 7,8-Dimethyltetradecane (2801-86-7)

Guidance literature:

With tetrabutylammonium tetrafluoroborate; nickel⁽⁰⁾ 2,2'-bipyridyl complex; Product distribution; electrochemical reduction;;

DOI:10.1016/0022-328X(86)80044-4

Reference yield:

oct-1-ene (111-66-0,25068-25-1) → octane (111-65-9) + cis-2-octene (7642-04-8) + trans-2-Octene (13389-42-9) + 7-methylpentadecane (6165-40-8) + 7,8-Dimethyltetradecane (2801-86-7)

Guidance literature:

With hydrogen; at -78 ℃; Product distribution; Mechanism; also deuterium and 1,6-heptadiene;

DOI:10.1021/ja00094a025

upstream raw materials:

ethyl sodium

(2R)-2-bromooctane

pentane

2-iodooctane

Refernces

• 1、 Gao, Fang,Boyles, David,Sullivan, Rodney,Compton, Robert N.,Pagni, Richard M.. "Photochemistry of racemic and resolved 2-iodooctane. Effect of solvent polarity and viscosity on the chemistry". . p. 9361 - 9367. Retrieved 2007/10/03.
• 2、 Tanner, Dennis D.,Zhang, Liying,Kandanarachchi, Pramod. "Absolute rate constants for the addition of atomic hydrogen to monosubstituted and trisubstituted olefins". . p. 11319 - 11324. Retrieved 2007/10/03.