Benzenamine, 4,4'-oxybis[N-(2-pyridinylmethylene)-

Base Information

• Chemical Name: Benzenamine, 4,4'-oxybis[N-(2-pyridinylmethylene)-
• CAS No.: 299396-82-0
• Molecular Formula: C24H18N4O
• Molecular Weight: 378.433
• Mol file: 299396-82-0.mol

Synonyms:

Chemical Property of Benzenamine, 4,4'-oxybis[N-(2-pyridinylmethylene)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Benzenamine, 4,4'-oxybis[N-(2-pyridinylmethylene)-

There total 1 articles about Benzenamine, 4,4'-oxybis[N-(2-pyridinylmethylene)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

2-nitrosopyridine (79917-37-6) + 4,4'-oxydiphenylene diamine (101-80-4,121509-79-3) → bis[4-(2-pyridylmethyleneamino)phenyl] ether (299396-82-0)

Guidance literature:

acetic acid; In dichloromethane; at 20 ℃;

Reference yield: 99.0%

bis[4-(2-pyridylmethyleneamino)phenyl] ether (299396-82-0) + copper(ll) sulfate pentahydrate → 6Cu(2+)*6O(C6H4NCHNC5H4)2*6SO4(2-)*24H2O=(Cu((C6H4NCHNC5H4)2O)(SO4))6*24H2O

Guidance literature:

In methanol; water; acetonitrile; ligand reacted with CuSO4*5H2O in CH3OH/H2O?CH3CN mixt.(2:1:2 v/v);

DOI:10.1039/b925469b

Reference yield: 77.0%

bis[4-(2-pyridylmethyleneamino)phenyl] ether (299396-82-0) + cis-bis-(2,2′-bipyridine) dichlororuthenium(II) dihydrate + sodium tetraphenyl borate (143-66-8) → [(Ru(2,2'-bipyridine)2)2(μ-bis(4-(2-pyridylmethyleneamino)phenyl)ether)](BPh4)4

Guidance literature:

With AgNO₃; In ethanol; byproducts: AgCl; under N2; soln. of AgNO3 (0.62 mmol) in EtOH added to soln. of Ru complex (0.32 mmol)in EtOH; mixt. refluxed for 30 min; AgCl filtered off; ligand (0.15 mmol) added to filtrate; soln. refluxed for 12 h; soln. added to soln. of NaBPh4 in EtOH; ppt. sepd. and dissolved in DMF; soln. added to EtOH; ppt. sepd., washedwith EtOH, and dried under vac. over P4O10; elem. anal.;

DOI:10.1039/b502656c

upstream raw materials:

2-nitrosopyridine

4,4'-oxydiphenylene diamine

Refernces