Benzene, 1,1'-sulfonylbis[3-azido-

Base Information

• Chemical Name: Benzene, 1,1'-sulfonylbis[3-azido-
• CAS No.: 75742-13-1
• Molecular Formula: C12H8N6O2S
• Molecular Weight: 300.301
• European Community (EC) Number: 278-300-8
• DSSTox Substance ID: DTXSID3072826
• Nikkaji Number: J319.133H
• Wikidata: Q82001066
• Mol file: 75742-13-1.mol

Synonyms:75742-13-1;3-AZIDOPHENYL SULFONE;Benzene, 1,1'-sulfonylbis[3-azido-;3,3'-Diazidodiphenyl sulfone;1-azido-3-(3-azidophenyl)sulfonylbenzene;3,3'-Diazidodiphenyl sulphone;EINECS 278-300-8;Benzene, 1,1'-sulfonylbis(3-azido-;m-Azidophenyl sulfone;Bis(3-azidophenyl) sulfone;Bis-(3-azidobenzen)-sulfon;3,3'-sulfonylbis(azidobenzene);DTXSID3072826;SCHEMBL18918246;Diphenylsulfone, 3,3'-diazido-;MFCD00043695;AKOS032953562;FT-0615086;1-AZIDO-3-(3-AZIDOBENZENESULFONYL)BENZENE

Chemical Property of Benzene, 1,1'-sulfonylbis[3-azido-

Chemical Property:

• Appearance/Colour: Yellow crystalline powder
• Melting Point: 110-114 °C
• Refractive Index: 1.7000 (estimate)
• PSA: 142.02000
• Density: 1.4492 (rough estimate)
• LogP: 4.38932
• Storage Temp.: 2-8°C
• XLogP3: 4.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 4
• Exact Mass: 300.04294469
• Heavy Atom Count: 21
• Complexity: 515

Purity/Quality:

99% ^*data from raw suppliers

3-Azidophenyl sulfone ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn
• Hazard Codes: Xn
• Statements: 20/22-36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC(=CC(=C1)S(=O)(=O)C2=CC=CC(=C2)N=[N+]=[N-])N=[N+]=[N-]

Technology Process of Benzene, 1,1'-sulfonylbis[3-azido-

There total 1 articles about Benzene, 1,1'-sulfonylbis[3-azido- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

3,3'-diaminodiphenyl sulfone (599-61-1) → 3,3'-Diazidodiphenylsulfon (75742-13-1)

Guidance literature:

3,3'-diaminodiphenyl sulfone; With hydrogenchloride; sodium nitrite; at 0 - 5 ℃; for 0.5h;

With sodium azide; at 0 - 5 ℃;

DOI:10.1021/ja051685b

Reference yield: 73.0%

3,3'-Diazidodiphenylsulfon (75742-13-1) → 3,3'-diaminodiphenyl sulfone (599-61-1)

Guidance literature:

With hydrazine hydrate; palladium dihydroxide; pyrographite; In methanol; for 2h; Heating;

DOI:10.1055/s-1989-27284

Reference yield:

4-O-propargyl-2-deoxystreptamine + 3,3'-Diazidodiphenylsulfon (75742-13-1) → C30H40N10O8S

Guidance literature:

With tetrakis(actonitrile)copper(I) hexafluorophosphate; In dimethyl sulfoxide; for 0.0111111h; microwave irradiation;

DOI:10.1021/ja051685b

upstream raw materials:

3,3'-diaminodiphenyl sulfone

Downstream raw materials:

3,3'-diaminodiphenyl sulfone

C₄₂H₆₄N₁₄O₁₄S

Refernces