Cyclopropylcyclohexane

Base Information

• Chemical Name: Cyclopropylcyclohexane
• CAS No.: 32669-86-6
• Molecular Formula: C9H16
• Molecular Weight: 124.2233
• Mol file: 32669-86-6.mol

Synonyms:Cyclohexane,cyclopropyl;Cyclohexyl-cyclopropan;Cyclohexylcyclopropane;Cyclopropyl-cyclohexan;

Chemical Property of Cyclopropylcyclohexane

Chemical Property:

• Vapor Pressure: 2.86mmHg at 25°C
• Boiling Point: 162.2°Cat760mmHg
• Flash Point: 35°C
• PSA: 0.00000
• Density: 0.931g/cm³
• LogP: 2.97670

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Cyclopropylcyclohexane

There total 10 articles about Cyclopropylcyclohexane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 41.0%

diazomethane (186581-53-3,908094-01-9,334-88-3) + vinylcyclohexane (695-12-5,25498-06-0) → cyclohexylcyclopropane (32669-86-6)

Guidance literature:

palladium(II) acetylacetonate; In diethyl ether; at -10 ℃;

DOI:10.1007/BF00956960

Reference yield:

1-Cyclopropyl-1-cyclohexanol (24321-70-8) → cyclohexylcyclopropane (32669-86-6)

Guidance literature:

With trifluoroacetic acid; HSiPh₃; In dichloromethane;

DOI:10.1021/ja01039a024

Reference yield:

cyclohexanone (108-94-1,11119-77-0,9003-41-2,9075-99-4) → cyclohexylcyclopropane (32669-86-6)

Guidance literature:

Multi-step reaction with 2 steps

1: (i) Li, Et₂O, (ii) /BRN= 385735/, (iii) H₂O

2: Ph₃SiH, CF₃CO₂H / CH₂Cl₂

With trifluoroacetic acid; HSiPh₃; In dichloromethane;

DOI:10.1021/ja01039a024

upstream raw materials:

1,3-Dibrom-2-cyclohexyl-propan

2,2-Dibrom-1-cyclohexyl-cyclopropan

1-Cyclopropyl-1-cyclohexanol

2-cyclohexylacetylene

Refernces

• 1、 Dzhemilev, U. M.,Dokichev, V. A.,Sultanov, S. Z.,Khusnutdinov, R. I.,Tomilov, Yu. V.,et al.. "REACTIONS OF DIAZOALKANES WITH UNSATURATED COMPOUNDS. 6. CATALYTIC CYCLOPROPANATION OF UNSATURATED HYDROCARBONS AND THEIR DERIVATIVES WITH DIAZOMETHANE". . p. 1707 - 1714. Retrieved 2007/10/02.