(2-Butenyl)methyl sulfide

Base Information

• Chemical Name: (2-Butenyl)methyl sulfide
• CAS No.: 32931-14-9
• Molecular Formula: C5H10S
• Molecular Weight: 102.2
• Mol file: 32931-14-9.mol

Synonyms:1-methylsulfanyl-but-2-ene;crotyl-methyl-sulfide;But-2-enyl-methylsulfid;1-Methylthio-2-buten;Crotyl Methyl Sulfide;

Chemical Property of (2-Butenyl)methyl sulfide

Chemical Property:

• PSA: 25.30000
• LogP: 1.92550

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (2-Butenyl)methyl sulfide

There total 5 articles about (2-Butenyl)methyl sulfide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

(Z)-2-Butene (590-18-1) + allylmethyl sulfide (10152-76-8) → 2-butenyl methyl sulfide (32931-14-9)

Guidance literature:

(2,6-Ph₂C₆H₃O)2W(Cl)=CHC(CH₃)3*OEt₂; In chlorobenzene; at 20 ℃; for 15h;

Reference yield: 95.0%

butene-2 (107-01-7) + allylmethyl sulfide (10152-76-8) → 2-butenyl methyl sulfide (32931-14-9)

Guidance literature:

With chloroaryloxide neopentylidene complex of tungsten ⁽¹⁾;

Reference yield: 52.0%

S-(1-methylallyl) S-methyl dithiocarbonate (40486-60-0,142109-03-3) → 2-butenyl methyl sulfide (32931-14-9)

Guidance literature:

at 210 ℃;

DOI:10.1248/cpb.38.619 DOI:10.1016/S0040-4039(00)98992-5

upstream raw materials:

methyl-(1-methyl-allyl)-disulfane

(Z)-2-Butene

allylmethyl sulfide

butene-2

Downstream raw materials:

2-hydroxy-3-butene

Refernces

• 1、 Couturier, Jean-Luc,Tanaka, Katsumi,Leconte, Michel,Basset, Jean-Marie. "OLEFIN METATHESIS: A NEW TOOL IN THE SYNTHESIS OF ORGANIC SULFUR COMPOUNDS". . p. 383 - 384. Retrieved 2007/10/02.
• 2、 Harano, Kazunobu,Ohizumi, Norihide,Hisano, Takuzo. "A CONVENIENT AND STEREOSELECTIVE SYNTHESIS OF ALLYLIC SULFIDES". . p. 4203 - 4206. Retrieved 2007/10/02.