Methanone, (2,6-dimethyl-1-naphthalenyl)phenyl

Base Information

• Chemical Name: Methanone, (2,6-dimethyl-1-naphthalenyl)phenyl
• CAS No.: 33121-77-6
• Molecular Formula: C19H16O
• Molecular Weight: 260.335
• Mol file: 33121-77-6.mol

Synonyms:

Chemical Property of Methanone, (2,6-dimethyl-1-naphthalenyl)phenyl

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Methanone, (2,6-dimethyl-1-naphthalenyl)phenyl

There total 3 articles about Methanone, (2,6-dimethyl-1-naphthalenyl)phenyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

→ 1-benzoyl-2,6-dimethylnaphthalene (33121-77-6)

Guidance literature:

With copper(II) bis(trifluoromethanesulfonate); In chloroform; water; at 65 ℃; for 18h; Sealed tube; Inert atmosphere;

Reference yield:

2.6-dimethylnaphthalene (581-42-0) + benzoyl chloride (98-88-4) → 4-benzoyl-2,6-dimethylnaphthalene (33121-76-5) + 1-benzoyl-2,6-dimethylnaphthalene (33121-77-6)

Guidance literature:

With bismuth(III) oxide; In various solvent(s); at 150 ℃; for 2.5h; Title compound not separated from byproducts;

DOI:10.1021/ol034529n

Reference yield:

2.6-dimethylnaphthalene (581-42-0) + benzoyl chloride (98-88-4) → 1-benzoyl-2,6-dimethylnaphthalene (33121-77-6)

Guidance literature:

With carbon disulfide; aluminium trichloride; at 0 ℃;

DOI:10.1039/jr9320000456

upstream raw materials:

2.6-dimethylnaphthalene

benzoyl chloride

Downstream raw materials:

3-methylbenz[a]anthracene

Refernces

• 1、 Gmouh, Said,Yang, Hongly,Vaultier, Michel. "Activation of bismuth(III) derivatives in ionic liquids: Novel and recyclable catalytic systems for Friedel-Crafts acylation of aromatic compounds". . p. 2219 - 2222. Retrieved 2007/10/03.