9,9-Dimethyl-N-phenyl-9H-fluoren-2-amine

Base Information

• Chemical Name: 9,9-Dimethyl-N-phenyl-9H-fluoren-2-amine
• CAS No.: 355832-04-1
• Molecular Formula: C21H19N
• Molecular Weight: 285.389
• Hs Code.: 2921499090
• DSSTox Substance ID: DTXSID90595874
• Nikkaji Number: J2.810.068J
• Wikidata: Q72470475
• Mol file: 355832-04-1.mol

Synonyms:9,9-Dimethyl-N-phenyl-9H-fluoren-2-amine;355832-04-1;9,9-DIMETHYL-N-PHENYLFLUOREN-2-AMINE;2-Anilino-9,9-dimethylfluorene;MFCD20040462;9,9-Dimethyl-2-(phenylamino)fluorene;N-(9,9-Dimethylfluoren-2-yl)aniline;9H-Fluoren-2-amine, 9,9-dimethyl-N-phenyl-;SCHEMBL783000;AMY8823;DTXSID90595874;RFTRFDMRINNTSI-UHFFFAOYSA-N;AKOS016008096;DS-4269;AC-28782;SY037124;DB-069233;(9,9-dimethyl-9H-fluoren-2-yl)phenylamine;CS-0148484;9,9-Dimethyl-N-phenyl-9H-fluoren-2-amine, 98%;A847491;J-519487;9,9-dimethyl-N-phenyl-9H-fluoren-2-amine

Chemical Property of 9,9-Dimethyl-N-phenyl-9H-fluoren-2-amine

Chemical Property:

• Melting Point: 99.0 to 103.0 °C
• Boiling Point: 448.7±24.0 °C(Predicted)
• PKA: 0.95±0.40(Predicted)
• PSA: 12.03000
• Density: 1.128
• LogP: 5.80950
• Storage Temp.: Keep in dark place,Inert atmosphere,Room temperature
• Solubility.: Chloroforom (Slightly), DMSO (Slightly), Ethyl Acetate (Slightly)
• XLogP3: 6
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 285.151749610
• Heavy Atom Count: 22
• Complexity: 381

Purity/Quality:

99.0% ^*data from raw suppliers

9,9-Dimethyl-N-phenyl-9H-fluoren-2-amine ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CC1(C2=CC=CC=C2C3=C1C=C(C=C3)NC4=CC=CC=C4)C
• Uses: 9,9-Dimethyl-N-phenyl-9H-fluoren-2-amine is useful for the synthetic preparation of secondary amines.

Technology Process of 9,9-Dimethyl-N-phenyl-9H-fluoren-2-amine

There total 5 articles about 9,9-Dimethyl-N-phenyl-9H-fluoren-2-amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

2-bromo-9,9-dimethyl-9H-fluorene (28320-31-2) + aniline (62-53-3) → N-phenyl-(9,9-dimethyl-9H-fluoren-2-yl)amine (355832-04-1)

Guidance literature:

With 1,1'-bis-(diphenylphosphino)ferrocene; palladium diacetate; sodium t-butanolate; In toluene; for 20h; Reflux; Inert atmosphere;

Reference yield: 89.4%

→ N-phenyl-(9,9-dimethyl-9H-fluoren-2-yl)amine (355832-04-1)

Guidance literature:

With palladium diacetate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; sodium t-butanolate; In toluene; for 12h; Inert atmosphere; Reflux;

Reference yield: 89.0%

C23H21NO → N-phenyl-(9,9-dimethyl-9H-fluoren-2-yl)amine (355832-04-1)

Guidance literature:

With triethyl borane; sodium hydroxide; In tert-butyl methyl ether; at 80 ℃; for 6h; Inert atmosphere; Sealed tube;

upstream raw materials:

2-bromo-9,9-dimethyl-9H-fluorene

aniline

bromobenzene

9,9-dimethyl-9H-fluoren-2-ylamine

Refernces

• 1、 -. "Organic compound, electronic device comprising organic compound and electronic equipment". Paragraph 0116-0118; 0119-0121. . Retrieved 2021/08/07.
• 2、 -. "Organic compound, and electronic element and electronic device using same". Paragraph 0150-0152; 0154. . Retrieved 2021/07/14.