Ethyl 3,4-dinitrobenzoate

Base Information

• Chemical Name: Ethyl 3,4-dinitrobenzoate
• CAS No.: 35998-99-3
• Molecular Formula: C₉H₈N₂O₆
• Molecular Weight: 240.172
• Hs Code.: 2916399090
• Mol file: 35998-99-3.mol

Synonyms:ETHYL 3,4-DINITROBENZOATE;3,4-Dinitro-benzoesaeure-aethylester;

Chemical Property of Ethyl 3,4-dinitrobenzoate

Chemical Property:

• Boiling Point: 411.1±30.0 °C(Predicted)
• PSA: 117.94000
• Density: 1.433±0.06 g/cm3(Predicted)
• LogP: 2.72610

Purity/Quality:

Ethyl 3,4-dinitrobenzoate >97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Ethyl 3,4-dinitrobenzoate

There total 6 articles about Ethyl 3,4-dinitrobenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

ethanol (64-17-5) + 3,4-dinitrobenzoic acid (528-45-0) → 3,4-dinitro-benzoic acid ethyl ester (35998-99-3)

Guidance literature:

With hydrogenchloride;

Reference yield:

1-methyl-3-nitrobenzene (99-08-1) → 3,4-dinitro-benzoic acid ethyl ester (35998-99-3)

Guidance literature:

Multi-step reaction with 3 steps

1: durch Nitrierung

2: bei der Oxydation

3: HCl

With hydrogenchloride;

Reference yield:

3,4-Dinitrotoluene (610-39-9) → 3,4-dinitro-benzoic acid ethyl ester (35998-99-3)

Guidance literature:

Multi-step reaction with 2 steps

1: bei der Oxydation

2: HCl

With hydrogenchloride;

upstream raw materials:

ethanol

3,4-dinitrobenzoic acid

3,4-dinitrobenzoyl chloride

ethyl iodide

Downstream raw materials:

2-methyl-1(3)H-benzoimidazole-5-carboxylic acid ethyl ester

Refernces

• 1、 Wang,Partch,Li. "Synthesis of 2-alkylbenzimidazoles via TiO2-mediated photocatalysis". . p. 5222 - 5225. Retrieved 2007/10/03.
• 2、 Kondo, Yasuhiko,Tsukamoto, Tamio,Moriguchi, Chika. "Single-ion enthalpies of transfer as a scale of nucleophilic reactivity towards ethyl iodide in acetonitrile". . p. 1699 - 1704. Retrieved 2007/10/03.