Chlorine atom

Base Information

• Chemical Name: Chlorine atom
• CAS No.: 22537-15-1
• Molecular Formula: Cl
• Molecular Weight: 35.453
• European Community (EC) Number: 826-865-1
• Mol file: 22537-15-1.mol

Synonyms:22537-15-1;Chlorine atom;Chlorine radical;chlorine(.);monochlorine;Cl(.);CHEBI:29311

Chemical Property of Chlorine atom

Chemical Property:

• PSA: 0.00000
• LogP: 0.68950
• XLogP3: 0.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 34.9688527
• Heavy Atom Count: 1
• Complexity: 0

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [Cl]

Technology Process of Chlorine atom

There total 237 articles about Chlorine atom which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

trichlorothiophosphine (3982-91-0) + water (7732-18-5) → PSCl2(1+) (52826-97-8) + clorine (14700-96-0,14835-24-6,15723-23-6,16547-50-5,16885-04-4,16887-00-6,16904-11-3,16904-12-4,16999-02-3,20337-89-7,20499-73-4,22537-15-1,22537-27-5,22541-73-7,22541-74-8,24203-47-2,33944-49-9,34937-26-3,37352-90-2)

Guidance literature:

In gas; High Pressure; the reagent ions were generated in an electron impact high-pressure ion source contg. H2O; the reagent ions were selected using a quadrupole mass filter before being injected into a drift region contg. helium carriergas; at 298 K; monitoring by quadrupole mass spectrometer at the end of the flow tube; Kinetics;

DOI:10.1016/j.chemphys.2004.03.033

Reference yield: 95.0%

chlorine azide → nitrene chloride (12190-75-9,10599-90-3) + clorine (14700-96-0,14835-24-6,15723-23-6,16547-50-5,16885-04-4,16887-00-6,16904-11-3,16904-12-4,16999-02-3,20337-89-7,20499-73-4,22537-15-1,22537-27-5,22541-73-7,22541-74-8,24203-47-2,33944-49-9,34937-26-3,37352-90-2)

Guidance literature:

In neat (no solvent); byproducts: N3, N2; Irradiation (UV/VIS); dominate products by 248-nm photolysis: Cl+N3, also observed NCl+N2; monitored by TOF MS;

DOI:10.1016/j.cplett.2004.04.113

Reference yield: 80.0%

chlorine (7782-50-5) → clorine (14700-96-0,14835-24-6,15723-23-6,16547-50-5,16885-04-4,16887-00-6,16904-11-3,16904-12-4,16999-02-3,20337-89-7,20499-73-4,22537-15-1,22537-27-5,22541-73-7,22541-74-8,24203-47-2,33944-49-9,34937-26-3,37352-90-2)

Guidance literature:

In neat (no solvent); flash photolysis;;

upstream raw materials:

tetrachloromethane

1,1,2,2-tetrachloroethylene

methylene chloride

Trichloroethylene

Downstream raw materials:

Iodine monochloride

hydroxyl

chloride

hydrogenchloride

Refernces

• 1、 Zhu, Jianqiang,Wang, Shuyan,Tsona, Narcisse T.,Jiang, Xiaotong,Wang, Yifeng,Ge, Maofa,Du, Lin. "Gas-Phase Reaction of Methyl n-Propyl Ether with OH, NO3, and Cl: Kinetics and Mechanism". . p. 6800 - 6809. Retrieved 2017/09/23.
• 2、 Boganov,Promyslov,Krylova,Zaitseva,Egorov. "Mechanism of thermal decomposition of allyltrichlorosilane with formation of three labile intermediates: dichlorosilylene, allyl radical, and atomic chlorine". . p. 1216 - 1224. Retrieved 2017/02/05.