methyl naphthalen-1-ylcarbamate

Base Information

• Chemical Name: methyl naphthalen-1-ylcarbamate
• CAS No.: 5449-00-3
• Molecular Formula: C12H11NO2
• Molecular Weight: 201.225
• Mol file: 5449-00-3.mol

Synonyms:

Chemical Property of methyl naphthalen-1-ylcarbamate

Chemical Property:

• Vapor Pressure: 0.00106mmHg at 25°C
• Boiling Point: 301.4°Cat760mmHg
• Flash Point: 136.1°C
• Density: 1.234g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of methyl naphthalen-1-ylcarbamate

There total 1 articles about methyl naphthalen-1-ylcarbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

methanol (67-56-1) + 1-Nitronaphthalene (86-57-7) + carbon monoxide (201230-82-2) → methyl 1-naphthylcarbamate (5449-00-3) + 1-amino-naphthalene (134-32-7)

Guidance literature:

With [2,2]bipyridinyl; dodecacarbonyl-triangulo-triruthenium; montmorillonitebipyridynylpalladium(II) acetate (Pd-clay); In benzene; at 180 ℃; for 24h; under 53200 Torr;

DOI:10.1021/ja00062a055

Reference yield: 98.0%

methyl 1-naphthylcarbamate (5449-00-3) + diphenyl acetylene (501-65-5) → methyl 2,3-diphenyl-1H-benzo[g]indole-1-carboxylate

Guidance literature:

With silver hexafluoroantimonate; dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; oxygen; copper(II) acetate monohydrate; In 1,2-dichloro-ethane; at 100 ℃; for 12h;

DOI:10.1021/ol502317c

Reference yield: 91.0%

methyl 1-naphthylcarbamate (5449-00-3) → 1-Naphthyl isocyanate (86-84-0)

Guidance literature:

With 2-chloro-1,3,2-benzodioxaborole; triethylamine; In toluene; 1.) reflux, 5 min, 2.) 0.5 h;

DOI:10.1021/jo00106a044

upstream raw materials:

methanol

1-Nitronaphthalene

carbon monoxide

Downstream raw materials:

1-amino-naphthalene

1-naphthyl isonitrile

1-Naphthyl isocyanate

8,9-dimethoxybenzo[c]phenanthridine

Refernces