Dihydrozeatin

Base Information

• Chemical Name: Dihydrozeatin
• CAS No.: 23599-75-9
• Molecular Formula: C10H15 N5 O
• Molecular Weight: 221.262
• European Community (EC) Number: 663-202-3
• DSSTox Substance ID: DTXSID90933510
• Nikkaji Number: J20.658J
• Wikidata: Q82909330
• Mol file: 23599-75-9.mol

Synonyms:dihydrozeatin

Chemical Property of Dihydrozeatin

Chemical Property:

• Vapor Pressure: 4.25E-13mmHg at 25°C
• Boiling Point: 553.8°Cat760mmHg
• PKA: 14.99±0.10(Predicted)
• Flash Point: 288.7°C
• PSA: 86.72000
• Density: 1.341g/cm³
• LogP: 0.85630
• Storage Temp.: 2-8°C
• XLogP3: 0.9
• Hydrogen Bond Donor Count: 3
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 5
• Exact Mass: 221.12766012
• Heavy Atom Count: 16
• Complexity: 215

Purity/Quality:

99% ^*data from raw suppliers

DL-Dihydrozeatin ≥98.0% (HPLC) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): 1215977
• Hazard Codes: Xi
• Statements: 43
• Safety Statements: 36/37

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CC(CCNC1=NC=NC2=C1NC=N2)CO

Technology Process of Dihydrozeatin

There total 2 articles about Dihydrozeatin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

dihydrozeatin riboside (22663-55-4) → dihydrozeatin (23599-75-9)

Guidance literature:

With recombinant Solanum tuberosum cytokinin riboside phosphorylase; In aq. buffer; at 30 ℃; for 0.333333h; pH=5.2; Kinetics; Enzymatic reaction;

DOI:10.1042/BJ20130792

Reference yield:

→ dihydrozeatin (23599-75-9)

Guidance literature:

DOI:10.1016/S0040-4039(01)85012-7 DOI:10.1016/0031-9422(79)80021-7 DOI:10.1021/ja00741a046 DOI:10.1016/S0031-9422(00)86698-4

Reference yield: 74.0%

dihydrozeatin (23599-75-9) + imidazole-1-carboxylic acid (2,5-dimethoxyphenyl)(2-nitrophenyl)methyl ester (1394141-19-5) → carbonic acid (2,5-dimethoxyphenyl)(2-nitrophenyl)methyl ester 2-methyl-4-(9H-purin-6-ylamino)butyl ester (1394141-21-9)

Guidance literature:

With caesium carbonate; In tetrahydrofuran; at 20 ℃;

DOI:10.1016/j.bmcl.2012.06.090

upstream raw materials:

dihydrozeatin riboside

Downstream raw materials:

dihydrozeatin-9-D-glucopyranoside

carbonic acid (2,5-dimethoxyphenyl)(2-nitrophenyl)methyl ester 2-methyl-4-(9H-purin-6-ylamino)butyl ester

carbonic acid 2-methyl-4-(9H-purin-6-ylamino)butyl ester naphthalen-1-yl-(2-nitrophenyl)methyl ester

dihydrozeatin riboside

Refernces

• 1、 Bromley, Jennifer R.,Warnes, Barbara J.,Newell, Christine A.,Thomson, Jamie C.P.,James, Celia M.,Turnbull, Colin G.N.,Hanke, David E.. "A purine nucleoside phosphorylase in Solanum tuberosum L. (potato) with specificity for cytokinins contributes to the duration of tuber endodormancy". . p. 225 - 237. Retrieved 2014/03/21.