2,4-Dinitrophenolate

Base Information

• Chemical Name: 2,4-Dinitrophenolate
• CAS No.: 20350-26-9
• Molecular Formula: C6H3N2O5-
• Molecular Weight: 183.1
• DSSTox Substance ID: DTXSID10174261
• Nikkaji Number: J395.816G
• Wikidata: Q27157865
• Mol file: 20350-26-9.mol

Synonyms:2,4-Dinitrophenolate;2,4-Dinitrophenol ion(1-);Phenol, 2,4-dinitro-, ion(1-);2,4-dinitrophenol(1-);20350-26-9;Fenoxyl;Tertrosulfur black pb;Dinitrophenol, 2,4-;SCHEMBL727425;C6H3N2O5;CHEBI:84561;DTXSID10174261;C6-H3-N2-O5;3-Thiomorpholinecarboxylic acid,5-methyl-,1-oxide;Q27157865

Chemical Property of 2,4-Dinitrophenolate

Chemical Property:

• Boiling Point: 312.1°Cat760mmHg
• Flash Point: 142.8°C
• Density: g/cm³
• XLogP3: 1.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 0
• Exact Mass: 183.00419620
• Heavy Atom Count: 13
• Complexity: 220

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC(=C(C=C1[N+](=O)[O-])[N+](=O)[O-])[O-]

Technology Process of 2,4-Dinitrophenolate

There total 391 articles about 2,4-Dinitrophenolate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2,4-dinitrophenyl 4-methoxybenzoate (24642-86-2) → 2,4-dinitrophenolate (20350-26-9) + 4-methoxybenzoic acid (100-09-4)

Guidance literature:

With hydroxide; In water; dimethyl sulfoxide; at 25 ℃; Kinetics; Alkaline hydrolysis;

DOI:10.1021/jo026339g

Reference yield:

2,4-dinitrophenyl benzenesulfonate (970-88-7) + ethylamine (75-04-7,85404-22-4) → N-ethylbenzenesulfonamide (5339-67-3) + 2,4-dinitrophenolate (20350-26-9)

Guidance literature:

In water; dimethyl sulfoxide; at 25 ℃; Kinetics;

DOI:10.1021/jo034190i

Reference yield:

ethylamine (75-04-7,85404-22-4) + 2,4-dinitrophenyl benzoate (1523-15-5) → N-ethylbenzamide (614-17-5) + 2,4-dinitrophenolate (20350-26-9)

Guidance literature:

In water; dimethyl sulfoxide; at 25 ℃; Kinetics;

DOI:10.1021/jo049694a

upstream raw materials:

pyrrolidine

(E)-O-(2,4-dinitrophenyl)benzaldoxime

piperidine

4-Chloro-benzaldehyde O-(2,4-dinitro-phenyl)-oxime

Downstream raw materials:

2,4-Dinitrophenol

2,2-difluoroacetate

N-butylamine

morpholine

Refernces

• 1、 Xavier, Fernando R.,Neves, Ademir. "Synthesis, physicochemical properties and in vitro catalytic activity of a dinuclear nickel(II) complex with a N5O-hexadentate ligand: A functional model for phosphohydrolases". . p. 59 - 66. Retrieved 2016.
• 2、 Ruschel Campedelli, Roberta,Keller, Mateus H.,Pinheiro, Gabriela,Campos, Carlos E. M.,Zaramello, Laize,Silveira De Souza, Bruno. "From the Shelf to the Particle: Preparation of Highly Organic-Functionalized Magnetic Composites via 4-Nitrophenyl Reactive Ester". . p. 9975 - 9983. Retrieved 2019.
• 3、 Maranha, Filipy Gobbo,dos Santos Silva, Graciela Aparecida,Bortoluzzi, Adailton J.,Nordlander, Ebbe,Peralta, Rosely A.,Neves, Ademir. "A new heteropentanuclear complex containing the [Fe2 IIIZn3 II(μ-OH)3] structural motif as a model for purple acid phosphatases". . . Retrieved 2020.
• 4、 Bunton, Clifford A.,Quan, Clifford. "Reaction of Bis(2,4-dinitrophenyl) Phosphate with Hydrophobic Ammonium Ions". . p. 5012 - 5015. Retrieved 1984.
• 5、 Bowden, Keith,Prasannan, Shyla. "Reactions in Strongly Basic Media. Part 8. Correlation of the Rates of Alkaline Hydrolysis of 2,4-Dinitroanisole and 2-Methoxy-5-nitropyridine in Aqueous Dipolar Aprotic Solvents with Acidity Functions. An Order of Basicity for Aqueous Dipolar Aprotic Solvents". . p. 185 - 188. Retrieved 1987.
• 6、 Khan, Shahid Ali,Rasool, Shagufta,Rahman, Khaliq Ur,Hussain, Shah,Khan, Inamullah,Ismail, Muhammad,Farooq, Aliya,Khan, Sarzamin,Raza, Mian Ahmad,Asiri, Abdullah Muhammad,Khan, Sher Bahadar. "A Simple but Efficient Catalytic Approach for the Degradation of Pollutants in Aqueous Media through Cicer arietinum Supported Ni Nanoparticles". . p. 1789 - 1802. Retrieved 2019/09/20.