Phosphoric acid, mono(2-hydroxypropyl) mono(4-nitrophenyl) ester, barium salt (2:1)

Base Information

• Chemical Name: Phosphoric acid, mono(2-hydroxypropyl) mono(4-nitrophenyl) ester, barium salt (2:1)
• CAS No.: 4286-25-3
• Molecular Formula: C9H12NO7P.1/2Ba
• Molecular Weight: 689.655
• Mol file: 4286-25-3.mol

Synonyms:

Chemical Property of Phosphoric acid, mono(2-hydroxypropyl) mono(4-nitrophenyl) ester, barium salt (2:1)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Phosphoric acid, mono(2-hydroxypropyl) mono(4-nitrophenyl) ester, barium salt (2:1)

There total 1 articles about Phosphoric acid, mono(2-hydroxypropyl) mono(4-nitrophenyl) ester, barium salt (2:1) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 28.0%

dicyclohexylammonium p-nitrophenyl phosphate (58965-74-5) + methyloxirane (75-56-9,16033-71-9) → 2-hydroxypropyl-4-nitrophenyl phosphate barium salt (4286-25-3)

Guidance literature:

dicyclohexylammonium p-nitrophenyl phosphate; methyloxirane; In water; at 30 ℃; for 72h;

With barium dihydroxide; In water; pH=6.8;

Reference yield:

2-hydroxypropyl-4-nitrophenyl phosphate barium salt (4286-25-3) → 4-nitro-phenol (100-02-7,78813-13-5,89830-32-0)

Guidance literature:

With 18-crown-6 ether; lutidine; water; In acetonitrile; at 25 ℃; Rate constant; other phosphodiesters; also in the presence of acylguanidinium salts;

DOI:10.1021/ja00029a068

Reference yield:

2-hydroxypropyl-4-nitrophenyl phosphate barium salt (4286-25-3) → 4-nitro-phenol (100-02-7,78813-13-5,89830-32-0) + 1,2 cyclic propanediol phosphate

Guidance literature:

With water; <(L2)Cu2(DBP)>(ClO4)2; at 25 ℃; Rate constant; pH 7.0; further catalyst;

upstream raw materials:

dicyclohexylammonium p-nitrophenyl phosphate

methyloxirane

Downstream raw materials:

4-nitro-phenol

p-nitrophenolate

2-hydroxypropyl-p-nitrophenyl phosphate

4-Methyl-2-oxo-2λ⁵-[1,3,2]dioxaphospholan-2-ol anion

Refernces