7-Oxabicyclo[4.1.0]hepta-1,3,5-triene

Base Information

• Chemical Name: 7-Oxabicyclo[4.1.0]hepta-1,3,5-triene
• CAS No.: 45467-78-5
• Molecular Formula: C6H4O
• Molecular Weight: 92.0972
• Mol file: 45467-78-5.mol

Synonyms:phenylene oxide;7-Oxa-bicyclo[4.1.0]hepta-1(6),2,4-triene;

Chemical Property of 7-Oxabicyclo[4.1.0]hepta-1,3,5-triene

Chemical Property:

• Boiling Point: 113.7±7.0 °C(Predicted)
• PSA: 9.23000
• Density: 1.243±0.06 g/cm3(Predicted)
• LogP: 1.35420

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 7-Oxabicyclo[4.1.0]hepta-1,3,5-triene

There total 2 articles about 7-Oxabicyclo[4.1.0]hepta-1,3,5-triene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4-chlorobenzonitrile (100-00-5) → cyclohexene oxide (45467-78-5)

Guidance literature:

With potassium carbonate; In methanol; nitrogen; N,N-dimethyl-formamide; toluene;

Reference yield:

6-Diazo-2,4-cyclohexadienon (4024-72-0,29124-78-5,29906-36-3) → cyclohexene oxide (45467-78-5)

Guidance literature:

Product distribution; Rate constant; laser flash photolysis in methanol or water;

DOI:10.1021/j100348a028

Reference yield:

carbon dioxide (124-38-9,18923-20-1) + cyclohexene oxide (45467-78-5) → 1,3-benzodioxol-2-one (2171-74-6)

Guidance literature:

With tetrabutylammomium bromide; at 80 ℃; for 5h; under 3750.38 Torr;

DOI:10.1016/j.ica.2020.119880

upstream raw materials:

6-Diazo-2,4-cyclohexadienon

4-chlorobenzonitrile

Downstream raw materials:

1,3-benzodioxol-2-one

Refernces

• 1、 Tanigaki, Katsumi,Ebbesen, Thomas W.. "DYnamics of the Wolf Rearrangement of Six-Membered Ring o-Diazo Ketones by Laser Flash Photolysis". . p. 4531 - 4536. Retrieved 2007/10/02.