Methanesulfonic acid, 1-Methylbutyl ester

Base Information

• Chemical Name: Methanesulfonic acid, 1-Methylbutyl ester
• CAS No.: 4551-09-1
• Molecular Formula: C6H14O3S
• Molecular Weight: 166.241
• Mol file: 4551-09-1.mol

Synonyms:methanesulfonic acid-(1-methyl-butyl ester);Methanesulfonic acid 1-methyl-butyl ester;2-Methansulfonyloxy-pentan;Methansulfonsaeure-(1-methyl-butylester);

Chemical Property of Methanesulfonic acid, 1-Methylbutyl ester

Chemical Property:

• Boiling Point: 253.7±9.0 °C(Predicted)
• PSA: 51.75000
• Density: 1.070±0.06 g/cm3(Predicted)
• LogP: 2.23200

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Methanesulfonic acid, 1-Methylbutyl ester

There total 3 articles about Methanesulfonic acid, 1-Methylbutyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(S)-2-pentanol (26184-62-3) + methanesulfonyl chloride (124-63-0) → pentan-2-yl methanesulfonate (4551-09-1)

Guidance literature:

With pyridine; at 0 ℃;

DOI:10.1021/ja01640a036

Reference yield:

(+/-)-2-pentanol (6032-29-7,13403-73-1) + methanesulfonyl chloride (124-63-0) → pentan-2-yl methanesulfonate (4551-09-1)

Guidance literature:

In pyridine; at 0 - 10 ℃;

DOI:10.1039/jr9650004097

Reference yield:

→ pentan-2-yl methanesulfonate (4551-09-1)

Guidance literature:

DOI:10.1021/jo01280a049

upstream raw materials:

(S)-2-pentanol

methanesulfonyl chloride

(+/-)-2-pentanol

Downstream raw materials:

diethyl ethyl(1-methyl-butyl)malonate

2,5-dimethyl-1-(1-methylbutyl)benzene

2,5-dimethyl-1-(1-ethylpropyl)benzene

2-phenylpentane

Refernces

• 1、 Zwierzak, Andrzej. "TRIETHYL PHOSPHITE IN ORGANIC SYNTHESIS. A FACILE, ONE-POT CONVERSION OF ALCOHOLS INTO AMINES". . p. 51 - 54. Retrieved 2007/10/02.