Pyridine, 4,4'-[[1,1'-biphenyl]-4,4'-diylbis(oxymethylene)]bis-

Base Information

• Chemical Name: Pyridine, 4,4'-[[1,1'-biphenyl]-4,4'-diylbis(oxymethylene)]bis-
• CAS No.: 469865-58-5
• Molecular Formula: C₂₄H₂₀N₂O₂
• Molecular Weight: 368.435
• Mol file: 469865-58-5.mol

Synonyms:

Chemical Property of Pyridine, 4,4'-[[1,1'-biphenyl]-4,4'-diylbis(oxymethylene)]bis-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Pyridine, 4,4'-[[1,1'-biphenyl]-4,4'-diylbis(oxymethylene)]bis-

There total 1 articles about Pyridine, 4,4'-[[1,1'-biphenyl]-4,4'-diylbis(oxymethylene)]bis- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

4,4'-Dihydroxybiphenyl (92-88-6) + 4-picolylchloride hydrochloride (1822-51-1) → 4,4'-bis(4-pyridin-4-ylmethoxy)biphenyl (469865-58-5)

Guidance literature:

4,4'-Dihydroxybiphenyl; With potassium tert-butylate; In N,N-dimethyl-formamide;

4-picolylchloride hydrochloride; In N,N-dimethyl-formamide; Further stages.;

DOI:10.1039/b110189g

Reference yield: 75.0%

cobalt(II) nitrate hexahydrate + 4,4'-bis(4-pyridin-4-ylmethoxy)biphenyl (469865-58-5) → [Co(4,4'-bis(pyridin-4-ylmethoxy)biphenyl)(NO3)2]

Guidance literature:

In methanol; chloroform; soln. Co(NO3)2*6H2O in MeCN was layered on soln. ligand in chloroform; soln. was concd., ppt. was filtered, washed with CHCl3 and dried in air;elem. anal.;

DOI:10.1039/b110189g

Reference yield: 45.0%

cobalt(II) nitrate hexahydrate + acetone (67-64-1) + 4,4'-bis(4-pyridin-4-ylmethoxy)biphenyl (469865-58-5) → [Co2(4,4'-bis(pyridin-4-ylmethoxy)biphenyl)4(NO3)4]*(Me2CO)2

Guidance literature:

In dichloromethane; acetone; soln. Co(NO3)2*6H2O in Me2CO was layered on soln. ligand in CH2Cl2; soln. was concd., ppt. was filtered, washed with acetone and dried in air; elem. anal.;

DOI:10.1039/b110189g

upstream raw materials:

4,4'-Dihydroxybiphenyl

4-picolylchloride hydrochloride

Refernces

• 1、 Banfi, Stefano,Carlucci, Lucia,Caruso, Enrico,Ciani, Gianfranco,Proserpio, Davide M.. "Using long bis(4-pyridyl) ligands designed for the self-assembly of coordination frameworks and architectures". . p. 2714 - 2721. Retrieved 2002.