D-Idose

Base Information

• Chemical Name: D-Idose
• CAS No.: 5978-95-0
• Molecular Formula: C6H12O6
• Molecular Weight: 180.158
• Hs Code.: 29400090
• European Community (EC) Number: 227-780-7
• Nikkaji Number: J1.575.935F
• Wikidata: Q106055850
• Metabolomics Workbench ID: 68763
• Mol file: 5978-95-0.mol

Synonyms:D-Ido;D-Idopyranose;D-Idopyranoside;D-Idose;D-Ido-hexose;d-(+)-idose;(3S,4R,5R,6R)-6-(hydroxymethyl)oxane-2,3,4,5-tetrol;AKOS006272407;AC1L9AFN;D-Idop;Idose, D-(8CI);SureCN78910;SCHEMBL78910;CHEBI:155878;C06466;W-203227;WURCS=2.0/1,1,0/[a1212h-1x_1-5]/1/;(3S,4R,5R,6R)-6-(hydroxymethyl)tetrahydropyran-2,3,4,5-tetrol;(3S,4R,5R,6R)-6-(hydroxymethyl)tetrahydro-2H-pyran-2,3,4,5-tetraol

Chemical Property of D-Idose

Chemical Property:

• Vapor Pressure: 1.83E-08mmHg at 25°C
• Refractive Index: 1.635
• Boiling Point: 527.1 °C at 760 mmHg
• Flash Point: 286.7 °C
• PSA: 110.38000
• Density: 1.581 g/cm³
• LogP: -3.22140
• Storage Temp.: -20°C
• Solubility.: DMSO (Slightly), Methanol (Slightly), Water (Slightly)
• XLogP3: -2.6
• Hydrogen Bond Donor Count: 5
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 1
• Exact Mass: 180.06338810
• Heavy Atom Count: 12
• Complexity: 151

Purity/Quality:

99%, ^*data from raw suppliers

D-Idose ^*data from reagent suppliers

Safty Information:

• Safety Statements: 24/25

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(C1C(C(C(C(O1)O)O)O)O)O
• Isomeric SMILES: C([C@@H]1[C@@H]([C@H]([C@@H](C(O1)O)O)O)O)O
• Uses: D-Idose is a monosaccharide that is an important component of dermatan sulfate and heparan sulfate.

Technology Process of D-Idose

There total 112 articles about D-Idose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

D-galactitol (608-66-2) + water (7732-18-5) → lyxo-2-hexulose (57-48-7,87-79-6,87-81-0,551-68-8,3615-39-2,3615-56-3,6035-50-3,7776-48-9,16354-64-6,17598-81-1,17598-82-2,23140-52-5,30237-26-4,65732-90-3,73952-10-0,73952-11-1,139686-85-4,18875-34-8) + galactose (50-99-7,59-23-4,921-60-8,1949-88-8,1990-29-0,2152-76-3,2595-97-3,2595-98-4,3458-28-4,4205-23-6,5934-56-5,5978-95-0,5987-68-8,6027-89-0,6038-51-3,7635-11-2,10030-80-5,15572-79-9,19163-87-2,23567-25-1,26566-61-0,30077-17-9,31103-86-3,39665-52-6,40866-07-7,58367-01-4,58407-05-9,58407-06-0,83198-69-0,83198-70-3,83198-71-4,93780-23-5,145920-48-5) + galactonic acid (133-42-6,488-33-5,526-95-4,526-97-6,576-36-3,642-99-9,1114-17-6,3956-93-2,6906-37-2,7760-07-8,13382-27-9,20246-33-7,20246-35-9,20246-52-0,20246-53-1,21675-42-3,22430-69-9,24871-35-0,28223-42-9,28278-17-3,51547-37-6)

Guidance literature:

at 80 ℃; weitere Produkte:2-Keto-DL-galaktonsaeure; DL-Galakturonsaeure;Schleimsaeure;

DOI:10.1021/ja01276a001

Reference yield:

galactonic acid (133-42-6,488-33-5,526-95-4,526-97-6,576-36-3,642-99-9,1114-17-6,3956-93-2,6906-37-2,7760-07-8,13382-27-9,20246-33-7,20246-35-9,20246-52-0,20246-53-1,21675-42-3,22430-69-9,24871-35-0,28223-42-9,28278-17-3,51547-37-6) → galactose (50-99-7,59-23-4,921-60-8,1949-88-8,1990-29-0,2152-76-3,2595-97-3,2595-98-4,3458-28-4,4205-23-6,5934-56-5,5978-95-0,5987-68-8,6027-89-0,6038-51-3,7635-11-2,10030-80-5,15572-79-9,19163-87-2,23567-25-1,26566-61-0,30077-17-9,31103-86-3,39665-52-6,40866-07-7,58367-01-4,58407-05-9,58407-06-0,83198-69-0,83198-70-3,83198-71-4,93780-23-5,145920-48-5)

Guidance literature:

das Lacton regiert;

Reference yield:

gluconic acid (133-42-6,488-33-5,526-95-4,526-97-6,576-36-3,642-99-9,1114-17-6,3956-93-2,6906-37-2,7760-07-8,13382-27-9,20246-33-7,20246-35-9,20246-52-0,20246-53-1,21675-42-3,22430-69-9,24871-35-0,28223-42-9,28278-17-3,51547-37-6) → glucose (50-99-7,59-23-4,921-60-8,1949-88-8,1990-29-0,2152-76-3,2595-97-3,2595-98-4,3458-28-4,4205-23-6,5934-56-5,5978-95-0,5987-68-8,6027-89-0,6038-51-3,7635-11-2,10030-80-5,15572-79-9,19163-87-2,23567-25-1,26566-61-0,30077-17-9,31103-86-3,39665-52-6,40866-07-7,58367-01-4,58407-05-9,58407-06-0,83198-69-0,83198-70-3,83198-71-4,93780-23-5,145920-48-5)

Guidance literature:

das Lacton reagiert;

upstream raw materials:

mannitol

para-xylene

water

1,2,3,4,6,-penta-O-acetyl-α-D-idopyranose

Downstream raw materials:

p-benzosemiquinone radical anion

tetra-O-acetyl-glucopyranosyl bromide

succinic acid

LACTIC ACID

Refernces

• 1、 Liu, Zilei,Jenkinson, Sarah F.,Yoshihara, Akihide,Wormald, Mark R.,Izumori, Ken,Fleet, George W.J.. "D-idose, d-iduronic acid, and D-idonic acid from D-glucose via seven-carbon sugars". . . Retrieved 2019.
• 2、 Dromowicz, Manfred,Koell, Peter. "A convenient synthesis of D-idose". . p. 169 - 171. Retrieved 1998.
• 3、 Qin, Ze,Zhang, Jin,Chen, Liang,Liu, Shu-Xiang,Zhao, Hai-Feng,Mao, Hui-Min,Zhang, Hong-Yang,Li, De-Fang. "Anti-inflammatory active components of the roots of Datura metel". . p. 392 - 398. Retrieved 2020/03/30.