Phosphoric acid vinyldiethyl ester

Base Information

• Chemical Name: Phosphoric acid vinyldiethyl ester
• CAS No.: 4851-64-3
• Molecular Formula: C6H13O4P
• Molecular Weight: 180.141
• Mol file: 4851-64-3.mol

Synonyms:Phosphoric acid,diethyl vinyl ester;phosphoric acid diethyl ester vinyl ester;Phosphorsaeure-diethylester-vinylester;Phosphoric acid,ethenyl diethyl ester;Diethyl vinyl phosphate;Diaethyl-vinyl-phosphat;Diethyl-vinyl-phosphat;Vinyl-diethyl-phosphat;Phosphorsaeure-diaethylester-vinylester;

Chemical Property of Phosphoric acid vinyldiethyl ester

Chemical Property:

• Boiling Point: 67 °C(Press: 2.5 Torr)
• PSA: 54.57000
• Density: 1.0724 g/cm3(Temp: 35 °C)
• LogP: 2.32760

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Phosphoric acid vinyldiethyl ester

There total 9 articles about Phosphoric acid vinyldiethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

tetrahydrofuran (109-99-9,24979-97-3,77392-70-2) + diethyl chlorophosphate (814-49-3) → phosphoric acid diethyl ester vinyl ester (4851-64-3)

Guidance literature:

tetrahydrofuran; With n-butyllithium; In hexane; at 0 - 25 ℃; for 18.5h;

diethyl chlorophosphate; at -78 - 20 ℃; for 0.75h;

DOI:10.1021/jo0513562

Reference yield:

n-butyllithium (109-72-8,29786-93-4) + diethyl chlorophosphate (814-49-3) → phosphoric acid diethyl ester vinyl ester (4851-64-3)

Guidance literature:

In tetrahydrofuran; hexane;

Reference yield:

2-bromoethyl diethyl phosphate (5314-05-6) → phosphoric acid diethyl ester vinyl ester (4851-64-3)

Guidance literature:

With diethyl ether; sodium hydride;

DOI:10.1021/ja01596a044

upstream raw materials:

2-bromoethyl diethyl phosphate

2-chloroethanal

triethyl phosphite

4-chloro-1,3-dioxolan-2-one

Downstream raw materials:

2,3,4,5-tetra-O-acetyl-D-glucopyranose

diethyl 2-(2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl)-ethylphosphonate

1-deoxy-D-glucose tetraacetate

1,3,4,6-tetra-O-acetyl-2-deoxy-α-D-arabinohexopyranose

Refernces

• 1、 -. "COMPOSITION THAT CAN BE CURED BY POLYMERISATION FOR THE PRODUCTION OF BIODEGRADABLE, BIOCOMPATIBLE, CROSS-LINKABLE POLYMERS ON THE BASIS OF POLYVINYL ALCOHOL". . . Retrieved 2010/12/29.