Cyclohexadeca-1,9-diene

Base Information

• Chemical Name: Cyclohexadeca-1,9-diene
• CAS No.: 4277-06-9
• Molecular Formula: C₁₆H₂₈
• Molecular Weight: 220.398
• European Community (EC) Number: 431-730-1
• Nikkaji Number: J891.887B
• Mol file: 4277-06-9.mol

Synonyms:trans cis-1 9-cyclohexadecadiene;(1E,9E)-cyclohexadeca-1,9-diene;110028-14-3;1,9-Cyclohexadecadiene;cyclohexadeca-1,9-diene;1,9-Cyclohexadecadiene #;(E,E)-1,9-cyclohexadecadiene;(1E,9E)-1,9-Cyclohexadecadiene;1,9-Cyclohexadecadiene, (E,E)-

Chemical Property of Cyclohexadeca-1,9-diene

Chemical Property:

• Vapor Pressure: 0.000814mmHg at 25°C
• Boiling Point: 315.3°Cat760mmHg
• Flash Point: 120.3°C
• Density: 0.814g/cm³
• XLogP3: 7.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 220.219100893
• Heavy Atom Count: 16
• Complexity: 146

Purity/Quality:

99.9% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1CCCC=CCCCCCCC=CCC1
• Isomeric SMILES: C1CC/C=C/CCCCCC/C=C/CCC1

Technology Process of Cyclohexadeca-1,9-diene

There total 27 articles about Cyclohexadeca-1,9-diene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 31.0%

C44H44P2 (38451-22-8) → 1,9-cyclohexadecene diene (4277-06-9,7431-74-5,7433-61-6,7433-62-7,110028-14-3)

Guidance literature:

With (Camphorylsulfonyl)oxaziridine ⁽⁴⁾; In tetrahydrofuran; at 25 ℃; for 0.5h;

DOI:10.1021/jo00288a066

Reference yield: 30.0%

cis-Cyclooctene (931-88-4,931-87-3,25267-51-0) → 1,9-cyclohexadecene diene (4277-06-9,7431-74-5,7433-61-6,7433-62-7,110028-14-3)

Guidance literature:

aluminum oxide; tetramethylstannane; rhenium(VII) oxide; In hexane; at 35 - 50 ℃;

DOI:10.1055/s-1987-28129

Reference yield:

1,2-cyclooctene (931-88-4,22770-27-0,3958-30-3,25267-51-0) → 1,9-cyclohexadecene diene (4277-06-9,7431-74-5,7433-61-6,7433-62-7,110028-14-3)

Guidance literature:

In cyclohexane; at 60 ℃; for 175h; under 760.051 Torr; Product distribution / selectivity; Inert atmosphere;

upstream raw materials:

cyclohexadeca-1,9-diyne

cis-Cyclooctene

1 ,6-dibromohexane

1,9-decadiyne

Downstream raw materials:

cyclohexadecane

(E/Z)-cyclohexa-dec-8-enone

hexadeca-8,15-dienal

3-methylcyclopentadecanone

Refernces

• 1、 Brown, Christopher C.,Rominger, Frank,Limbach, Michael,Hofmann, Peter. "Bulky N-Phosphino-Functionalized N-Heterocyclic Carbene Ligands: Synthesis, Ruthenium Coordination Chemistry, and Ruthenium Alkylidene Complexes for Olefin Metathesis". . p. 10126 - 10140. Retrieved 2015/11/16.
• 2、 Samantaray, Manoja K.,Alauzun, Johan,Gajan, David,Kavitake, Santosh,Mehdi, Ahmad,Veyre, Laurent,Lelli, Moreno,Lesage, Anne,Emsley, Lyndon,Copéret, Christophe,Thieuleux, Chloé. "Evidence for metal-surface interactions and their role in stabilizing Well-defined immobilized Ru-NHC alkene metathesis catalysts". . p. 3193 - 3199. Retrieved 2013/04/23.