1,4-Cyclohexadiene-1-sulfonic acid, 3,6-dioxo-, potassium salt

Base Information

• Chemical Name: 1,4-Cyclohexadiene-1-sulfonic acid, 3,6-dioxo-, potassium salt
• CAS No.: 51368-42-4
• Molecular Formula: C6H4O5S.K
• Molecular Weight: 226.251
• Mol file: 51368-42-4.mol

Synonyms:

Chemical Property of 1,4-Cyclohexadiene-1-sulfonic acid, 3,6-dioxo-, potassium salt

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1,4-Cyclohexadiene-1-sulfonic acid, 3,6-dioxo-, potassium salt

There total 2 articles about 1,4-Cyclohexadiene-1-sulfonic acid, 3,6-dioxo-, potassium salt which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4-Methyl-4-(hydroxymethyl)-1-phenyl-3-pyrazolidone radical (118713-88-5) + potassium 2,5-dihydroxybenzene sulfonate (21799-87-1) → 3,6-dioxo-cyclohexa-1,4-dienesulfonic acid ; potassium-salt (51368-42-4) + 4-methyl-4-hydroxymethyl-1-phenyl-3-pyrazolidinone (13047-13-7)

Guidance literature:

In water; at 25 ℃; Rate constant; Equilibrium constant; dependence on pH;

DOI:10.1021/ja00187a045

Reference yield:

potassium 2,5-dihydroxybenzene sulfonate (21799-87-1) → 3,6-dioxo-cyclohexa-1,4-dienesulfonic acid ; potassium-salt (51368-42-4)

Guidance literature:

With sulfuric acid; oxygen; In water; at 30 ℃; under 836.056 Torr; Reagent/catalyst;

DOI:10.1021/jacs.1c11126

upstream raw materials:

4-Methyl-4-(hydroxymethyl)-1-phenyl-3-pyrazolidone radical

potassium 2,5-dihydroxybenzene sulfonate

Refernces

• 1、 Youngblood, Michael P.. "Kinetics of Electron-Transfer Reactions of Hydroquinones and Ascorbic Acid with 1-Phenyl-3-pyrazolidone Radicals". . p. 1843 - 1849. Retrieved 2007/10/02.