2-Butenedioic acid, di-2-propynyl ester

Base Information

• Chemical Name: 2-Butenedioic acid, di-2-propynyl ester
• CAS No.: 53024-63-8
• Molecular Formula: C₁₀H₈O₄
• Molecular Weight: 192.171
• Mol file: 53024-63-8.mol

Synonyms:

Chemical Property of 2-Butenedioic acid, di-2-propynyl ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-Butenedioic acid, di-2-propynyl ester

There total 2 articles about 2-Butenedioic acid, di-2-propynyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 22.0%

propargyl alcohol (107-19-7) + 2-butenedioic acid (6915-18-0,26099-09-2) → diprop-2-ynyl fumarate (53024-63-8)

Guidance literature:

With dmap; dicyclohexyl-carbodiimide; In N,N-dimethyl-formamide; at 20 ℃; for 48h; Inert atmosphere;

DOI:10.1039/c5cc05117g

Reference yield:

→ diprop-2-ynyl fumarate (53024-63-8)

Guidance literature:

Maleinsaeureanhydrid, Propargylalkohol, sd. Bzl., Toluol-4-sulfonsaeure;

Reference yield: 68.0%

diprop-2-ynyl fumarate (53024-63-8) → di(prop-2-yn-1-yl) succinate (4580-40-9)

Guidance literature:

With water; 5-methoxy-1,3,4-triphenyl-4,5-dihydro-1H-1,2-4-triazoline; In 1,2-dimethoxyethane; at 150 ℃; for 2h; Inert atmosphere; Microwave irradiation;

DOI:10.1039/c5cc05117g

upstream raw materials:

propargyl alcohol

2-butenedioic acid

Downstream raw materials:

di(prop-2-yn-1-yl) succinate

Refernces