Bismuth (III) acetate

Base Information

• Chemical Name: Bismuth (III) acetate
• CAS No.: 22306-37-2
• Molecular Formula: C₆H₉BiO₆
• Molecular Weight: 386.114
• Hs Code.: 29159000
• NSC Number: 370498
• Mol file: 22306-37-2.mol

Synonyms:Acetic acid, bismuth salt;bismuth (iii) acetate;SCHEMBL149554;NSC370498;NSC-370498

Chemical Property of Bismuth (III) acetate

Chemical Property:

• Appearance/Colour: white scaly crystalline
• Vapor Pressure: 13.9mmHg at 25°C
• Melting Point: decomposes [CRC10]
• Boiling Point: 117.1 °C at 760 mmHg
• Flash Point: 40 °C
• PSA: 37.30000
• LogP: 0.42840
• Storage Temp.: Inert atmosphere,Room Temperature
• Sensitive.: Hygroscopic
• Water Solubility.: Soluble in water.
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 269.00153
• Heavy Atom Count: 5
• Complexity: 31

Purity/Quality:

98%,99%, ^*data from raw suppliers

Bismuth(III) acetate, 99% ^*data from reagent suppliers

Safty Information:

• Statements: 36/37/38
• Safety Statements: 26-36-24/25

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CC(=O)O.[Bi]
• Uses: Bismuth(III) acetate is used in biology, printing, in photographic films, textiles, and also in proteomics research.

Technology Process of Bismuth (III) acetate

There total 17 articles about Bismuth (III) acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

acetic anhydride (108-24-7) + bismuth(III) oxide (1304-76-3) → bismuth(III) acetate (22306-37-2,29094-03-9,36476-26-3,73206-34-5)

Guidance literature:

In acetic anhydride; acetic acid; byproducts: acetic acid; soln. of oxide in a mixt. of acetic anhydride (100 ml) and acetic acid (100 ml), refluxed (1.5 h), cooled (0°C), crystn.; filtration (Buechner funnel); elem. anal.;

Reference yield: 95.0%

bismuth (III) nitrate pentahydrate + acetic anhydride (108-24-7) → bismuth(III) acetate (22306-37-2,29094-03-9,36476-26-3,73206-34-5)

Guidance literature:

In acetic anhydride; acetic acid; byproducts: acetic acid, NO2, O2; soln. of oxide in a mixt. of acetic anhydride (100 ml) and acetic acid (100 ml), refluxed (1.5 h), cooled (0°C), crystn.; filtration (Buechner funnel); elem. anal.;

Reference yield:

triphenylbismuthane (603-33-8) → bismuth(III) acetate (22306-37-2,29094-03-9,36476-26-3,73206-34-5)

Guidance literature:

copper diacetate; In toluene; byproducts: C6H6; react. for 12h at 50°C, absence of air;

upstream raw materials:

acetic anhydride

acetic acid

mannitol

copper diacetate

Downstream raw materials:

t-2-iodo-2-methylcyclohexan-r-1-yl acetate

3α-methyl-2β-iodo-1α-acetoxycyclohexane

(1α,2β,3β)-2-iodo-3-methylcyclohexyl acetate

(1α,2β,3β)-3-methylcyclohexane-1,2-diyl diacetate

Refernces

• 1、 -. "Preparation of 2,5-dimethyl-4-hydroxy-2,3-dihydrofuran-3-one". . . Retrieved 2008/06/13.