Technology Process of Homopterocarpin
There total 1 articles about Homopterocarpin which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
Multi-step reaction with 3 steps
1: 59 percent / Ti(IV)Cl4/Ti(OiPr)4 / CH2Cl2 / -78 - -25 °C
2: 87 percent / pyridine / CH2Cl2 / -70 - 20 °C
3: 92 percent / Et3NHO2CH, Pd(OAc)2, 1,1'-bis(diphenylphosphino)ferrocene / dimethylformamide / 74 °C
With
pyridine; 1,1'-bis-(diphenylphosphino)ferrocene; palladium diacetate; triethylammonium formate;
titanium(IV) isopropylate; titanium tetrachloride;
In
dichloromethane; N,N-dimethyl-formamide;
DOI:10.1039/C39890000454
- Guidance literature:
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Multi-step reaction with 6 steps
1: H2 / Pd-C / ethanol
2: 250 mg / Adogen 464
3: 150 mg / 2,3-dichloro-5,6-dicyano-1,4-benzoquinone / methanol / 36 h / 25 °C
4: 49 mg / NaBH4 / tetrahydrofuran; ethanol / 12 h / 25 °C
5: 52 mg / pyridine
6: 30 mg / ethyl acetate / 32 h / Irradiation
With
pyridine; sodium tetrahydroborate; adogen 464; hydrogen; 2,3-dicyano-5,6-dichloro-p-benzoquinone;
palladium on activated charcoal;
In
tetrahydrofuran; methanol; ethanol; ethyl acetate;
- Guidance literature:
-
With
hydrogen;
palladium on activated charcoal;
In
ethanol;
