2-Hexene, 2-(butylthio)-, (Z)-

Base Information

• Chemical Name: 2-Hexene, 2-(butylthio)-, (Z)-
• CAS No.: 54796-99-5
• Molecular Formula: C10H20S
• Molecular Weight: 172.335
• Mol file: 54796-99-5.mol

Synonyms:

Chemical Property of 2-Hexene, 2-(butylthio)-, (Z)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-Hexene, 2-(butylthio)-, (Z)-

There total 8 articles about 2-Hexene, 2-(butylthio)-, (Z)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 10.0%

n-Butyl chloride (109-69-3) → dibutyl disulfide (629-45-8) + (1-methyl)-1Z-pentenyl butyl sulfide (54796-99-5) + (1-methyl)-1E-pentenyl butyl sulfide (54796-97-3) + 2,4-dibutylthiophene (123707-64-2)

Guidance literature:

With sulfur; Co(acac)2-PPh₃-AlEt₃; In N,N-dimethyl-formamide; toluene; at 130 ℃; for 9h; Further byproducts given. Yields of byproduct given;

DOI:10.1007/BF00958250

Reference yield:

n-Butyl chloride (109-69-3) → symmetric dibutylthiophene (6911-45-1) + dibutyl disulfide (629-45-8) + (1-methyl)-1Z-pentenyl butyl sulfide (54796-99-5) + (1-methyl)-1E-pentenyl butyl sulfide (54796-97-3)

Guidance literature:

With sulfur; hex-1-yne; triethylaluminum; triphenylphosphine; cobalt acetylacetonate; In N,N-dimethyl-formamide; at 130 ℃; for 6h; Further byproducts given;

DOI:10.1007/BF00960174

Reference yield:

hex-1-yne (693-02-7) → symmetric dibutylthiophene (6911-45-1) + dibutyl disulfide (629-45-8) + (1-methyl)-1Z-pentenyl butyl sulfide (54796-99-5) + (1-methyl)-1E-pentenyl butyl sulfide (54796-97-3)

Guidance literature:

With sulfur; Co(acac)2-PPh₃-AlEt₃; In N,N-dimethyl-formamide; toluene; at 130 ℃; for 9h; Yield given. Further byproducts given. Yields of byproduct given;

DOI:10.1007/BF00958250

upstream raw materials:

n-Butyl chloride

hex-1-yne

Refernces

• 1、 Dzhemilev, U. M.,Baibulatova, N. Z.,Tkachenko, T. K.,Kunakova, R. V.. "AN ORIGINAL METHOD FOR THE PREPARATION OF SULFIDES AND DISULFIDES INVOLVING COBALT COMPLEXES". . p. 1782. Retrieved 2007/10/02.