7,10-Diphenylfluoranthene

Base Information

• Chemical Name: 7,10-Diphenylfluoranthene
• CAS No.: 55087-78-0
• Molecular Formula: C28H18
• Molecular Weight: 354.451
• DSSTox Substance ID: DTXSID10457425
• Nikkaji Number: J1.337.436H
• Wikidata: Q82280267
• Mol file: 55087-78-0.mol

Synonyms:7,10-diphenylfluoranthene

Chemical Property of 7,10-Diphenylfluoranthene

Chemical Property:

• PSA: 0.00000
• LogP: 7.82120
• XLogP3: 7.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 2
• Exact Mass: 354.140850574
• Heavy Atom Count: 28
• Complexity: 478

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C2=C3C4=CC=CC5=C4C(=CC=C5)C3=C(C=C2)C6=CC=CC=C6

Technology Process of 7,10-Diphenylfluoranthene

There total 22 articles about 7,10-Diphenylfluoranthene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

1,8-bis-(phenylethynyl)naphthalene (17694-87-0) + bicyclo[2.2.1]hepta-2,5-diene (121-46-0) → 7,10-diphenylfluoranthene (55087-78-0)

Guidance literature:

[(1,5-cyclooctadiene)₂RhCl]₂; In xylene; at 80 ℃;

DOI:10.1021/ol0514799

Reference yield: 91.0%

(7,10-diphenylfluoranthen-8-yl)trimethylsilane (1246675-16-0) → 7,10-diphenylfluoranthene (55087-78-0)

Guidance literature:

With hydrogenchloride; In tetrahydrofuran; water; for 10h; Reflux;

DOI:10.1039/c3ra47751g

Reference yield: 76.0%

tetrathiafulvalene (31366-25-3) + acecyclone (641-57-6) → 7,10-diphenylfluoranthene (55087-78-0)

Guidance literature:

In 5,5-dimethyl-1,3-cyclohexadiene; for 16h; Inert atmosphere; Reflux;

DOI:10.1021/acs.orglett.7b03686

upstream raw materials:

vinyl acetate

acecyclone

Vinyl bromide

-butyl vinyl ether

Refernces

• 1、 Wang, Hua,Liang, Yan,Wang, Yike,Xie, Huanling,Feng, Linglong,Lu, Haifeng,Feng, Shengyu. "The strategy to improve thermal and optical properties of diphenylfluoranthene based on silicon-cored derivatives". . p. 17171 - 17178. Retrieved 2014/05/06.
• 2、 Wu, Yao-Ting,Hayama, Tomoharu,Baldridge, Kim K.,Linden, Anthony,Siegel, Jay S.. "Synthesis of fluoranthenes and indenocorannulenes: Elucidation of chiral stereoisomers on the basis of static molecular bowls". . p. 6870 - 6884. Retrieved 2007/10/03.