5H-Tetrazolium,3,4-dihydro-2,3-diphenyl-5-thioxo-, inner salt

Base Information

• Chemical Name: 5H-Tetrazolium,3,4-dihydro-2,3-diphenyl-5-thioxo-, inner salt
• CAS No.: 11065-31-9
• Molecular Formula: C13H10 N4 S
• Molecular Weight: 254.315
• Mol file: 11065-31-9.mol

Synonyms:1H-Tetrazolium,2,5-dihydro-2,3-diphenyl-5-thioxo-, inner salt (9CI); 5-Tetrazolidinethione,2,3-diphenyl-, meso-ionic didehydro deriv. (8CI); Dithizone, dehydro- (7CI);2,3-Diphenyltetrazolium-5-thiolate; 5-Mercapto-2,3-diphenyl-2H-tetrazoliumhydroxide, inner salt; Dehydrodithizone

Chemical Property of 5H-Tetrazolium,3,4-dihydro-2,3-diphenyl-5-thioxo-, inner salt

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 5H-Tetrazolium,3,4-dihydro-2,3-diphenyl-5-thioxo-, inner salt

There total 9 articles about 5H-Tetrazolium,3,4-dihydro-2,3-diphenyl-5-thioxo-, inner salt which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

1,5-diphenyl-thiocarbazone (60-10-6) → 2,3-diphenyl-2,3-dihydrotetrazolium-5-thiolate (11065-31-9)

Guidance literature:

With dihydrogen peroxide; In acetone; at 40 - 60 ℃; for 3h;

DOI:10.1021/jo0504767

Reference yield:

bis(1,5-diphenylformazan-3-yl) disulfide (25210-27-9) → 2,3-diphenyl-2,3-dihydrotetrazolium-5-thiolate (11065-31-9) + 1,5-diphenyl-thiocarbazone (60-10-6)

Guidance literature:

DOI:10.1016/j.poly.2010.02.009

Reference yield:

3-mercapto-1,5-diphenylformazan (60-10-6) → 2,3-diphenyl-2,3-dihydrotetrazolium-5-thiolate (11065-31-9)

Guidance literature:

With ammonia; dihydrogen peroxide; In chloroform; water; for 1h;

DOI:10.1039/b008263p

upstream raw materials:

1,5-diphenyl-thiocarbazone

3-mercapto-1,5-diphenylformazan

benzenediazonium

3-nitro-1,5-diphenylformazan

Downstream raw materials:

3'-phenyl-5'-phenylazo-2-piperidin-1-yl-3'H-spiro[indene-1,2'-[1,3,4]thiadiazole]

2-morpholin-4-yl-3'-phenyl-5'-phenylazo-3'H-spiro[indene-1,2'-[1,3,4]thiadiazole]

N-(1,2-diphenyldiazonia)-1,3-benzothiazole-2-aminate

5-carboxymethylthio-2,3-diphenyltetrazolium chloride

Refernces

• 1、 Ogilvie,Corwin. "-". . p. 5023,5026. Retrieved 1961.
• 2、 Jian, Fangfang,Zhao, Pusu,Zhang, Lan,Hou, Yuxia. "Synthesis of 2,3-diaryltetrazole-5-thiones and theoretical studies on atomic charge distributions of 2,3-diphenyltetrazole-5-thione". . p. 8322 - 8326. Retrieved 2007/10/03.
• 3、 Hutton, Alan T.,Irving, Harry M. N. H.. "Isomers of 3-Methylthio-1,5-diarylformazans and their Interconversion in Solution". . p. 1117 - 1122. Retrieved 2007/10/02.