4-Benzoylphenyl methacrylate

Base Information

• Chemical Name: 4-Benzoylphenyl methacrylate
• CAS No.: 56467-43-7
• Molecular Formula: C17H14O3
• Molecular Weight: 266.296
• European Community (EC) Number: 611-390-2
• DSSTox Substance ID: DTXSID801019359
• Nikkaji Number: J875.345H
• ChEMBL ID: CHEMBL9631
• Mol file: 56467-43-7.mol

Synonyms:4-benzoylphenyl methacrylate;56467-43-7;(4-benzoylphenyl) 2-methylprop-2-enoate;4-methacryloyloxybenzophenone;CHEMBL9631;4-benzoylphenylmethacrylate;4-methacryloyloxy-benzophenone;SCHEMBL144013;2-Propenoic acid, 2-methyl-, 4-benzoylphenyl ester;4-(methacryloyloxy)benzophenone;RYWGNBFHIFRNEP-UHFFFAOYSA-N;DTXSID801019359;AMY18883;BDBM50023512;MFCD30470334;BS-51839;B6151;2-Methyl-acrylic acid 4-benzoyl-phenyl ester;F71473

Chemical Property of 4-Benzoylphenyl methacrylate

Chemical Property:

• Vapor Pressure: 3.34E-07mmHg at 25°C
• PSA: 43.37000
• LogP: 3.39910
• XLogP3: 4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 5
• Exact Mass: 266.094294304
• Heavy Atom Count: 20
• Complexity: 372

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=C)C(=O)OC1=CC=C(C=C1)C(=O)C2=CC=CC=C2

Technology Process of 4-Benzoylphenyl methacrylate

There total 4 articles about 4-Benzoylphenyl methacrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.7%

methacryloyl anhydride (760-93-0) + 4-Hydroxybenzophenone (1137-42-4) → 4-hydroxybenzophenone ester of metacrylic acid (56467-43-7)

Guidance literature:

With 2,4-dimethyl-6-tert-butylphenol; sulfuric acid; 4-methoxy-phenol; at 90 ℃; for 6h; Air introduction;

Reference yield: 90.0%

4-Hydroxybenzophenone (1137-42-4) + Methacryloyl chloride (920-46-7,26937-45-1) → 4-hydroxybenzophenone ester of metacrylic acid (56467-43-7)

Guidance literature:

In acetone; at 0 ℃;

DOI:10.1039/c1sm05222e

Reference yield:

methacrylic acid methyl ester (80-62-6,114512-63-9,143476-91-9,25188-98-1,9011-14-7) + 4-Hydroxybenzophenone (1137-42-4) → 4-hydroxybenzophenone ester of metacrylic acid (56467-43-7)

Guidance literature:

With methacryloyl anhydride; 2,4-dimethyl-6-tert-butylphenol; sodium methylate; In methanol; at 60 - 90 ℃; for 6h; Reagent/catalyst;

upstream raw materials:

4-Hydroxybenzophenone

Methacryloyl chloride

methacryloyl anhydride

methanol

Refernces

• 1、 Barnes, Michael,Bisnoff, Phoebe,Emrick, Todd,Hayward, Ryan C.,Hight-Huf, Nicholas,Kang, Ji-Hwan,Kim, Hyunki,Sundararajan, Suvin,Thompson, Theo. "Polymer Zwitterions for Stabilization of CsPbBr3 Perovskite Nanoparticles and Nanocomposite Films". . p. 10802 - 10806. Retrieved 2020.
• 2、 -. "PREPARATION OF (METH)ACRYLIC ACID ESTERS". Page/Page column 18-19. . Retrieved 2020/03/05.
• 3、 -. "PHOTOACTIVATABLE FOULING-RESISTANT COPOLYMERS". Paragraph 00146; 00147. . Retrieved 2017/03/14.