tert-Butylhydrazine hydrochloride

Base Information

• Chemical Name: tert-Butylhydrazine hydrochloride
• CAS No.: 7400-27-3
• Molecular Formula: C4H13ClN2
• Molecular Weight: 124.614
• Hs Code.: 29280000
• Mol file: 7400-27-3.mol

Synonyms:Hydrazine,(1,1-dimethylethyl)-, monohydrochloride (9CI);Hydrazine, tert-butyl-,hydrochloride (6CI,7CI);Hydrazine, tert-butyl-, monohydrochloride (8CI);(1,1-Dimethylethyl)hydrazine hydrochloride;N'-tert-Butylhydrazinehydrochloride;tert-Butylhydrazinemonohydrochloride;tert-Butylhydrazinium chloride;

Chemical Property of tert-Butylhydrazine hydrochloride

Chemical Property:

• Appearance/Colour: White crystals or crystalline powder
• Vapor Pressure: 7.89mmHg at 25°C
• Melting Point: 191-194 °C(lit.)
• Boiling Point: 135 °C at 760 mmHg
• Flash Point: 35.8 °C
• PSA: 38.05000
• LogP: 2.14140
• Storage Temp.: Keep in dark place,Sealed in dry,Room Temperature
• Sensitive.: Hygroscopic
• Solubility.: DMSO, Methanol
• Water Solubility.: Solubility in water (almost transparency). Soluble in DMSO and methanol.
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 1
• Exact Mass: 124.0767261
• Heavy Atom Count: 7
• Complexity: 35.3

Purity/Quality:

98%,99, ^*data from raw suppliers

tert-Butylhydrazine Hydrochloride ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36-24/25

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CC(C)(C)N[NH3+].[Cl-]
• Uses: It is used in organic synthesis for aromatic nucleophilic N-N exchange reaction. tert-Butylhydrazine Hydrochloride is also used in the preparation of insect growth regulator. tert-Butylhydrazine hydrochloride was used in the synthesis of diphosphinohydrazines, 5-amino-1-tert-butyl-3-(p-chlorophenyl)-4-cyanopyrazole and 1,3,4,5-tetrasubstituted pyrazole derivatives.

Technology Process of tert-Butylhydrazine hydrochloride

There total 6 articles about tert-Butylhydrazine hydrochloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

N,N'-di-tert-butylhydrazine hydrochloride (13952-70-0) → tertbutylhydrazine hydrochloride (7400-27-3)

Guidance literature:

With hydrogenchloride; for 0.25h; Heating;

Reference yield: 71.0%

P,1,2-Tri-tert-butylhydrazidophosphonsaeure-tert-butylester (79371-20-3) → tertbutylhydrazine hydrochloride (7400-27-3)

Guidance literature:

With hydrogenchloride; for 0.25h; Heating;

Reference yield: 70.0%

→ tertbutylhydrazine hydrochloride (7400-27-3)

Guidance literature:

With hydrogenchloride; In dichloromethane; at 20 ℃; for 4h;

upstream raw materials:

P,1,2-Tri-tert-butylhydrazidophosphonsaeure-tert-butylester

N,N'-di-tert-butylhydrazine hydrochloride

P,1,2-Tri-tert-butylhydrazidophosphonsaeure-methylester

di-tert-butyl 1-(tert-butyl)hydrazine-1,2-dicarboxylate

Downstream raw materials:

N'-t-butylhydrazinecarboxylic acid ethyl ester

N-(di-p-cresylphosphinoyl)-N'-t-butylhydrazine

N--N'-t-butylhydrazine

N-benzylidene-N'-tert-butylhydrazine

Refernces

• 1、 -. "Synthesis method for pharmaceutically acceptable salt of alkylhydrazine". Paragraph 0038; 0048; 0057; 0058. . Retrieved 2017/08/28.