naphthalen-1-yl(phenyl)methanethione

Base Information

• Chemical Name: naphthalen-1-yl(phenyl)methanethione
• CAS No.: 33083-79-3
• Molecular Formula: C17H12S
• Molecular Weight: 248.348
• Mol file: 33083-79-3.mol

Synonyms:

Chemical Property of naphthalen-1-yl(phenyl)methanethione

Chemical Property:

• Vapor Pressure: 1.49E-06mmHg at 25°C
• Boiling Point: 409.9°Cat760mmHg
• Flash Point: 201.7°C
• Density: 1.185g/cm³

Purity/Quality:

99%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of naphthalen-1-yl(phenyl)methanethione

There total 2 articles about naphthalen-1-yl(phenyl)methanethione which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-benzoylnaphthalene (642-29-5) → naphthalen-1-yl(phenyl)methanethione (33083-79-3)

Guidance literature:

With diethyl ether; ethanol; benzene; at -10 - -5 ℃; weitere Reagentien: H₂S und HCl; anschliessend Behandeln mit H₂S bei 0grad;

DOI:10.1021/ja01311a006

Reference yield:

→ naphthalen-1-yl(phenyl)methanethione (33083-79-3)

Guidance literature:

aus Naphthalin-1-yl-carbonitril mit 1) PhLi 2) CS2;

Reference yield: 68.0%

N-benzyloxy-α-methyl-α-bromopropionamide (1303507-75-6) + naphthalen-1-yl(phenyl)methanethione (33083-79-3) → 3-(benzyloxy)-5,5-dimethyl-2-(naphthalen-1-yl)-2-phenylthiazolidin-4-one

Guidance literature:

With N-ethyl-N,N-diisopropylamine; at 20 ℃; Inert atmosphere;

DOI:10.1021/acs.orglett.9b01933

upstream raw materials:

1-benzoylnaphthalene

Downstream raw materials:

4-Phenyl-2H-3-thia-phenanthrene-1-carbonitrile

1-benzoylnaphthalene

2-Methoxy-4-phenyl-2H-3-thia-phenanthrene-1-carbonitrile

2-Ethoxy-4-phenyl-2H-3-thia-phenanthrene-1-carbonitrile

Refernces

• 1、 Arjunan, P,Ramamurthy, V,Venkatesan, K. "Gas-Solid Reactions: Photochemical Oxidation of Thioketones in the Crystalline State". . p. 1765 - 1769. Retrieved 2007/10/02.