1,1'-DIADAMANTYL

Base Information

• Chemical Name: 1,1'-DIADAMANTYL
• CAS No.: 3732-31-8
• Molecular Formula: C20H30
• Molecular Weight: 270.458
• Hs Code.: 2902199090
• Mol file: 3732-31-8.mol

Synonyms:1,1-Biadamantane;1,1'-BIADAMANTANE;1,1'-DIADAMANTYL;

Chemical Property of 1,1'-DIADAMANTYL

Chemical Property:

• Melting Point: 296℃
• Boiling Point: 359.9 °C at 760 mmHg
• Flash Point: 154.9 °C
• PSA: 0.00000
• Density: 1.117 g/cm³
• LogP: 5.41920
• Storage Temp.: 2-8°C

Purity/Quality:

99%, ^*data from raw suppliers

1,1''-Bi(tricyclo[3.3.1.1~3,7~]decane) ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1,1'-DIADAMANTYL

There total 41 articles about 1,1'-DIADAMANTYL which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

acetonitrile (75-05-8,26809-02-9) + trans-N,N'-bis(1-adamantyl)diazene (24325-56-2) → 1,1'-Biadamantane (3732-31-8) + adamantane (281-23-2) + N-(1-adamantyl)acetamide (880-52-4) + 1-acetyladamantane (1660-04-4)

Guidance literature:

With thianthrenium perchlorate; Further byproducts given; Ambient temperature;

DOI:10.1021/ja00294a066

Reference yield: 90.0%

acetonitrile (75-05-8,26809-02-9) + trans-N,N'-bis(1-adamantyl)diazene (24325-56-2) → 1,1'-Biadamantane (3732-31-8) + 1-adamanthanol (768-95-6) + N-(1-adamantyl)acetamide (880-52-4) + 1-acetyladamantane (1660-04-4)

Guidance literature:

With thianthrenium perchlorate; Further byproducts given; Ambient temperature;

DOI:10.1021/ja00294a066

Reference yield: 85.0%

1-Adamantyl bromide (768-90-1) → 1,1'-Biadamantane (3732-31-8)

Guidance literature:

With chloromethyldiphenylsilane; lithium; In tetrahydrofuran; for 0.5h; Ambient temperature;

upstream raw materials:

1-Adamantyl bromide

N-(diphenylmethylidene)phenylamine

diethyl ether

methyl adamantane-1-carboxylate

Downstream raw materials:

3,5,7,3',5',7'-Hexamethyl-[1,1']bi[tricyclo[decyl]

3,3'-dibromo-1,1'-biadamantane

1.1'-Biadamantyl-3.3'.5.5'-tetracarbonsaeure

1,1'-Bi(7-methylenebicyclo<3.3.1>nonan-3-one)

Refernces

• 1、 Jacobs, Brian P.,Wolczanski, Peter T.,Jiang, Quan,Cundari, Thomas R.,MacMillan, Samantha N.. "Rare Examples of Fe(IV) Alkyl-Imide Migratory Insertions: Impact of Fe - C Covalency in (Me2IPr)Fe(=NAd)R2 (R = neoPe, 1-nor)". . p. 12145 - 12148. Retrieved 2017.
• 2、 Farcasiu, Dan,Ghenciu, Anca,Li, Jing Qi. "The mechanism of conversion of saturated hydrocarbons catalyzed by sulfated metal oxides: Reaction of adamantane on sulfated zirconia". . p. 116 - 127. Retrieved 1996.
• 3、 Butov, G. M.,Mokhov, V. M.,Zubovich, E. A.. "Chemical Transformations of Tetracyclo[3.3.1.13,7.01,3]decane (1,3-Dehydroadamantane): IX. Noncatalytic Reactions with Alkylarenes". . p. 1041 - 1045. Retrieved 2020/07/25.