gamma-Terpineol

Base Information

• Chemical Name: gamma-Terpineol
• CAS No.: 586-81-2
• Molecular Formula: C10H18O
• Molecular Weight: 154.252
• European Community (EC) Number: 209-584-3
• UNII: 5PH9U7XEWS
• DSSTox Substance ID: DTXSID2060416
• Nikkaji Number: J9.439K
• Wikidata: Q27155106
• NCI Thesaurus Code: C80899
• Metabolomics Workbench ID: 47567
• Mol file: 586-81-2.mol

Synonyms:gamma-terpineol

Chemical Property of gamma-Terpineol

Chemical Property:

• Vapor Pressure: 0.027mmHg at 25°C
• Melting Point: 69 °C
• Refractive Index: 1.49
• Boiling Point: 218.2 °C at 760 mmHg
• PKA: 15.20±0.20(Predicted)
• Flash Point: 88.6 °C
• PSA: 20.23000
• Density: 0.941g/cm³
• LogP: 2.64780
• XLogP3: 2.1
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 154.135765193
• Heavy Atom Count: 11
• Complexity: 165

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=C1CCC(CC1)(C)O)C

Technology Process of gamma-Terpineol

There total 11 articles about gamma-Terpineol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

methyl magnesium iodide (917-64-6) + 4-(propan-2-ylidene)cyclohexan-1-one (19620-36-1) → γ-terpineol (586-81-2)

Guidance literature:

With diethyl ether;

Reference yield:

cis-4-hydroxy-α,α,4-trimethyl-cyclohexanemethanol, monohydrate (2451-01-6) → γ-terpineol (586-81-2)

Guidance literature:

With sulfuric acid;

Reference yield:

1-methyl-4-(1-methylethylidene)cyclohexanol acetate (10235-63-9) → γ-terpineol (586-81-2) + 1-acetoxy-p-menth-3-en-8-ol (88663-73-4) + 1-acetoxy-p-menth-4(8)-en-9-ol (88437-32-5)

Guidance literature:

at 25 ℃; for 48h; Yield given. Further byproducts given. Yields of byproduct given; Nicotiana tabacum culture cells, dark;

DOI:10.1039/P19830002475

upstream raw materials:

methyl magnesium iodide

4-(propan-2-ylidene)cyclohexan-1-one

cis-4-hydroxy-α,α,4-trimethyl-cyclohexanemethanol, monohydrate

ethanol

Downstream raw materials:

Terpinolene

4-hydroxy-4-methylcyclohexanone

1,4-dichloro-p-menthane

1,4-dichloro-trans-p-menthane

Refernces

• 1、 Corma, A.,Iglesias, M.,Sanchez, F.. "Large Pore Bifunctional Titanium-Aluminosilicates: the Inorganic Non-enzymatic Version of the Epoxidase Conversion of Linalool to Cyclic Ethers". . p. 1635 - 1636. Retrieved 2007/10/02.
• 2、 Lee, Ym Sook,Hirata, Toshifumi,Suga, Takayuki. "Biotransformation of 1-Acetoxy-p-menth-4(8)-ene with a Suspension of Cultured Cells of Nicotiana tabacum". . p. 2475 - 2478. Retrieved 2007/10/02.