cyclopentyl 4-methoxybenzoate

Base Information

• Chemical Name: cyclopentyl 4-methoxybenzoate
• CAS No.: 5421-01-2
• Molecular Formula: C13H16 O3
• Molecular Weight: 220.268
• Mol file: 5421-01-2.mol

Synonyms:NSC 6628

Chemical Property of cyclopentyl 4-methoxybenzoate

Chemical Property:

• Vapor Pressure: 0.00016mmHg at 25°C
• Boiling Point: 331°Cat760mmHg
• Flash Point: 136.6°C
• Density: 1.12g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of cyclopentyl 4-methoxybenzoate

There total 11 articles about cyclopentyl 4-methoxybenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

C16H7Cl4NO5 + cyclopentene (142-29-0) → cyclopentyl-p-methoxybenzoate (5421-01-2)

Guidance literature:

With fac-tris(2-(4,6-difluorophenyl)pyridinato,N,C(2'))iridium(III); In dichloromethane; at 20 ℃; for 24h; regioselective reaction; Irradiation;

DOI:10.1021/acscatal.1c03969

Reference yield: 75.0%

Cyclopentanol (96-41-3) + 4-methoxybenzoic acid (100-09-4) → cyclopentyl-p-methoxybenzoate (5421-01-2)

Guidance literature:

With diphenylphosphinopolystyrene; diethylazodicarboxylate; In tetrahydrofuran; at 25 ℃; for 4h;

DOI:10.1021/jo00168a058

Reference yield: 70.0%

(4-methoxyphenyl)dimethylsulfonium triflate + carbon monoxide (201230-82-2) + Cyclopentanol (96-41-3) → cyclopentyl-p-methoxybenzoate (5421-01-2)

Guidance literature:

With C₃₉H₃₂OP₂*C₁₃H₁₂N^(1-)*Pd⁽²⁺⁾*CH₃O₃S^(1-); N-ethyl-N,N-diisopropylamine; In toluene; at 110 ℃; for 12h; under 760.051 Torr; Inert atmosphere;

DOI:10.1021/acs.orglett.9b00067

upstream raw materials:

Cyclopentanol

4-methoxybenzoic acid

Cyclopentyl bromide

4-methoxy-benzaldehyde

Refernces

• 1、 Guo, Jiarui,Liu, Lantao,Wang, Tao,Wang, Yanqing,Xu, Kai,Zhang, Yuheng. "Transition-Metal-Free DMAP-Mediated Aromatic Esterification of Amides with Organoboronic Acids". supporting information. p. 3274 - 3277. Retrieved 2021/06/26.
• 2、 Minami, Hiroko,Nogi, Keisuke,Yorimitsu, Hideki. "Palladium-Catalyzed Alkoxycarbonylation of Arylsulfoniums". supporting information. p. 2518 - 2522. Retrieved 2019/04/17.