1-ISOPROPYL-O-CARBORANE

Base Information

• Chemical Name: 1-ISOPROPYL-O-CARBORANE
• CAS No.: 13569-38-5
• Molecular Formula: C5H18 B10
• Molecular Weight: 186.308
• Mol file: 13569-38-5.mol

Synonyms:1,2-Dicarbadodecaborane(12),1-isopropyl- (7CI,8CI); 1-Isopropyl-o-carborane; 1-Isopropyl-o-carborane(12); Isopropyl-o-carborane;Isopropylcarborane

Chemical Property of 1-ISOPROPYL-O-CARBORANE

Chemical Property:

• Melting Point: -16.9 °C
• Boiling Point: 98-99 °C(Press: 2 Torr)
• PSA: 0.00000
• Density: 0.9665 g/cm3
• LogP: -4.78320

Purity/Quality:

95%-98% ^*data from raw suppliers

1-ISOPROPYL-ORTHO-CARBORANE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1-ISOPROPYL-O-CARBORANE

There total 4 articles about 1-ISOPROPYL-O-CARBORANE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

1-isopropyl-ortho-carboranyllithium (56792-36-0) + arsenic trichloride (7784-34-1) → 1-isopropyl-ortho-closocarborane-12 (13569-38-5) + (2-isopropyl-o-carbaboran-1-yl)arsonous dichloride (80489-44-7) + bis(2-isopropyl-o-carbaboran-1-yl)arsinous chloride (80489-46-9)

Guidance literature:

In diethyl ether; benzene; byproducts: LiCl; inert atmosphere: addn. of carbaborane in benzene to etheral AsCl3, boiling (6 h); filtration, evapn. to dryness, treatmenr with hexane; elem. anal.;

Reference yield:

C8H26B10Si → 1-isopropyl-ortho-closocarborane-12 (13569-38-5)

Guidance literature:

With tetrabutyl ammonium fluoride; In tetrahydrofuran; at -78 - 20 ℃; for 2h; Inert atmosphere; Schlenk technique;

DOI:10.1016/j.cclet.2021.05.062

Reference yield:

2-benzoyl-1-isopropyl-o-carborane (23841-63-6) → 1-isopropyl-ortho-closocarborane-12 (13569-38-5)

Guidance literature:

With sodium amide; In ethanol;

upstream raw materials:

2-benzoyl-1-isopropyl-o-carborane

(2-isopropyl-o-carbaboran-1-yl)arsonous dichloride

1-isopropyl-ortho-carboranyllithium

arsenic trichloride

Refernces