N,N-Dimethyltridecylamine

Base Information

• Chemical Name: N,N-Dimethyltridecylamine
• CAS No.: 17373-29-4
• Molecular Formula: C15H33 N
• Molecular Weight: 227.434
• Hs Code.: 2921199090
• European Community (EC) Number: 266-922-2,241-410-1
• UNII: 9SJ2K327HZ
• DSSTox Substance ID: DTXSID0058510
• Nikkaji Number: J287.031B
• Wikidata: Q81976874
• Mol file: 17373-29-4.mol

Synonyms:N,N-Dimethyltridecylamine;17373-29-4;N,N-dimethyltridecan-1-amine;Tridecyldimethylamine;1-Tridecanamine, N,N-dimethyl-;1-(Dimethylamino)tridecane;N,N-Dimethylamino)tridecane;9SJ2K327HZ;EINECS 241-410-1;dodecyltrimethylamine;UNII-9SJ2K327HZ;N-TRIDECYLDIMETHYLAMINE;N,N-Dimethyl-1-tridecanamine;SCHEMBL284520;DTXSID0058510;N,N-Dimethyl-1-tridecanamine #;EINECS 266-922-2;N,N-Dimethyltridecylamine, >=97.0%;SDA 15-040-00;SDA 150-40-00;FT-0742329;J-010939;67700-98-5

Chemical Property of N,N-Dimethyltridecylamine

Chemical Property:

• Vapor Pressure: 0.00364mmHg at 25°C
• Melting Point: -61.15°C (estimate)
• Refractive Index: n20/D 1.439
• Boiling Point: 281.1°Cat760mmHg
• PKA: 9.78±0.28(Predicted)
• Flash Point: 116.2°C
• PSA: 3.24000
• Density: 0.802g/cm³
• LogP: 4.85900
• XLogP3: 6.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 12
• Exact Mass: 227.261300057
• Heavy Atom Count: 16
• Complexity: 121

Purity/Quality:

98%,99%, ^*data from raw suppliers

N,N-Dimethyltridecylamine ≥97.0% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 38
• Safety Statements: 23-24/25

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCCCCCCCCN(C)C

Technology Process of N,N-Dimethyltridecylamine

There total 6 articles about N,N-Dimethyltridecylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

dodec-6-ene (29493-00-3) + carbon monoxide (201230-82-2) → 2-methylundecyl-dimethylamine + 2-pentylheptyl-dimethylamine + 2-butylnonyl-dimethylamine + 2-ethylundecyl-dimethylamine + 2-methyldodecyl-dimethylamine + 2-propyldecyl-dimethylamine + 2-pentyloctyl-dimethylamine + N,N-dimethylaminododecane (112-18-5,83855-86-1) + dimethyl-(2-propyl-nonyl)-amine + (2-ethyl-decyl)-dimethyl-amine (42521-72-2) + (2-butyl-octyl)-dimethyl-amine (42521-73-3) + 1-(dimethylamino)tridecane (17373-29-4)

Guidance literature:

With hydrogen; rhodium(III) oxide; triphenylphosphine; at 150 ℃; for 20h; under 57005.7 Torr; Product distribution / selectivity;

Reference yield:

methanol (67-56-1) + 1-tridecanamine (2869-34-3) → 1-(dimethylamino)tridecane (17373-29-4)

Guidance literature:

With platinum on carbon; sodium hydroxide; at 150 ℃; for 36h; under 750.075 Torr; Inert atmosphere; Autoclave;

DOI:10.1016/j.jcat.2019.01.027

Reference yield:

→ 1-(dimethylamino)tridecane (17373-29-4)

Guidance literature:

With hydrogen; palladium on activated charcoal; at 25 ℃; under 2280 Torr; Yield given;

DOI:10.1021/jo00172a018

upstream raw materials:

1-dodecene

bis-(dimethylamino)methane

dodec-6-ene

carbon monoxide

Downstream raw materials:

triethylamine

Refernces

• 1、 Fa?bach, Thiemo A.,Kirchmann, Robin,Behr, Arno,Vorholt, Andreas J.. "Recycling of homogeneous catalysts in reactive ionic liquid-solvent-free aminofunctionalizations of alkenes". supporting information. p. 5243 - 5249. Retrieved 2017/11/09.
• 2、 Cohen, Theodore,Onopchenko, Anatoli. "Competing Hydride Transfer and Ene Reactions in the Aminoalkylation of 1-Alkenes with N,N-Dimethylmethyleniminium Ions. A Literature Correction". . p. 4531 - 4537. Retrieved 2007/10/02.