Butyl glycidyl ether

Base Information

• Chemical Name: Butyl glycidyl ether
• CAS No.: 2426-08-6
• Deprecated CAS: 85858-60-2,144376-83-0,921213-37-8,2560549-27-9,342395-38-4,144376-83-0,921213-37-8
• Molecular Formula: C7H14O2
• Molecular Weight: 130.187
• Hs Code.: 29109000
• European Community (EC) Number: 219-376-4
• ICSC Number: 0115
• NSC Number: 83413
• UN Number: 1993
• UNII: M03777A62S
• DSSTox Substance ID: DTXSID9024691
• Nikkaji Number: J35.202K
• Wikipedia: N-Butyl_glycidyl_ether
• Wikidata: Q2404890
• ChEMBL ID: CHEMBL1530010
• Mol file: 2426-08-6.mol

Synonyms:Oxirane,(butoxymethyl)- (9CI);Propane, 1-butoxy-2,3-epoxy- (6CI,8CI);(Butoxymethyl)oxirane;Oxirane,2-(butoxymethyl)-;1-Butyl glycidyl ether;2,3-Epoxypropyl butyl ether;2-(Butoxymethyl)oxirane;3-Butoxy-1,2-epoxypropane;Butyl 2,3-epoxypropylether;Butyl glycidyl ether;DY-BP;DY-BP (epoxide);Epi-Rez 501;Epiol B 4;Epodil 741HP;Epogosey BA;Glycidyl n-butyl ether;Laproxid 201B;NSC 83413;

Chemical Property of Butyl glycidyl ether

Chemical Property:

• Appearance/Colour: colourless liquid
• Vapor Pressure: 1.43mmHg at 25°C
• Melting Point: 59 °C
• Refractive Index: n20/D 1.418(lit.)
• Boiling Point: 176.999 °C at 760 mmHg
• Flash Point: 54.444 °C
• PSA: 21.76000
• Density: 0.945 g/cm³
• LogP: 1.20190
• Storage Temp.: Store below +30°C.
• Sensitive.: Moisture Sensitive
• Solubility.: 20g/l
• Water Solubility.: 2 g/100 mL
• XLogP3: 1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 5
• Exact Mass: 130.099379685
• Heavy Atom Count: 9
• Complexity: 73.3
• Transport DOT Label: Flammable Liquid

Purity/Quality:

99% ^*data from raw suppliers

Butyl Glycidyl Ether ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn
• Hazard Codes: Xn,T
• Statements: 10-20/22-37-40-43-52/53-68-20/21/22-45-36/37/38-23/24/25
• Safety Statements: 24/25-36/37-61-45-53-26

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Plastics & Rubber -> Glycidyl Ethers
• Canonical SMILES: CCCCOCC1CO1
• Inhalation Risk: A harmful contamination of the air can be reached rather quickly on evaporation of this substance at 20 °C.
• Effects of Short Term Exposure: The substance is irritating to the eyes, skin and respiratory tract.
• Effects of Long Term Exposure: Repeated or prolonged contact may cause skin sensitization. May cause heritable genetic damage to human germ cells.
• Description: n-Butyl glycidyl ether is a reactive diluent used to reduce viscosity of epoxy res ins Bisphenol A type.
• Uses: Viscosity-reducing agent, acid acceptor for solvents, chemical intermediate Uses include the roles of viscosity-reducing agent for easier handling of conventional epoxy resins, acid acceptor for stabilizing chlorinated solvents, and chemical intermediate. Some curing agents may produce hazardous polymerizations in large quantities.

Technology Process of Butyl glycidyl ether

There total 18 articles about Butyl glycidyl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

epichlorohydrin (106-89-8,24969-06-0,13403-37-7) + butan-1-ol (71-36-3) → glycidyl n-butyl ether (2426-08-6)

Guidance literature:

With sodium hydroxide; tetra(n-butyl)ammonium hydrogensulfate; for 3.5h; below 25 deg C;

DOI:10.1055/s-1983-30243

Reference yield: 75.0%

3-n-butoxy-1,2-propanediol (98451-40-2,119066-32-9,119066-33-0,624-52-2) → glycidyl n-butyl ether (2426-08-6)

Guidance literature:

With sodium hydroxide; methanesulfonyl chloride; N-benzyl-N,N,N-triethylammonium chloride; In dichloromethane; for 0.166667h; Heating;

DOI:10.1055/s-1985-31416

Reference yield: 68.0%

allyl n-butyl ether (3739-64-8) → glycidyl n-butyl ether (2426-08-6)

Guidance literature:

With perchloric acid; dihydrogen peroxide; In water; acetonitrile; tert-butyl alcohol; at 60 ℃; for 1h; stereoselective reaction;

DOI:10.1016/j.cattod.2011.07.007

upstream raw materials:

epichlorohydrin

3-n-butoxy-1,2-propanediol

1-chloro-3-n-butoxy-2-propanol

allyl n-butyl ether

Downstream raw materials:

acetic acid-(3-butoxy-2-hydroxy-propylamide)

1-diethylamino-3-butoxy-2-propanole

5-butoxymethyl-3-p-tolyl-oxazolidin-2-one

C₂₇H₄₇Cl₃O₆Si

Refernces

• 1、 Tang, Bo,Sun, Chenyu,Wang, Wei,Geng, Lina,Sun, Liquan,Luo, Aiqin. "Chiral amorphous metal–organic polyhedra used as the stationary phase for high-resolution gas chromatography separations". . p. 1178 - 1185. Retrieved 2020/07/09.
• 2、 -. "ANTIMICROBIAL AGENT CONTAINING POLYALKYLENEIMINE DERIVATIVE". . . Retrieved 2017/09/23.