3-Phenanthrenecarbaldehyde

Base Information

• Chemical Name: 3-Phenanthrenecarbaldehyde
• CAS No.: 7466-50-4
• Molecular Formula: C15H10O
• Molecular Weight: 206.2393
• Hs Code.: 2912299000
• Mol file: 7466-50-4.mol

Synonyms:phenanthrene-3-carboxaldehyde;3-Formyl-phenanthren;3-phenanthrene carboxaldehyde;Phenanthren-9-aldehyd;Phenanthren-3-carbaldehyd;3-phenanthrenecarbaldehyde;

Chemical Property of 3-Phenanthrenecarbaldehyde

Chemical Property:

• Vapor Pressure: 8.58E-07mmHg at 25°C
• Boiling Point: 405.7°Cat760mmHg
• Flash Point: 269.2°C
• PSA: 17.07000
• Density: 1.217g/cm³
• LogP: 3.80550

Purity/Quality:

98.5% ^*data from raw suppliers

3-PHENANTHRENECARBOXALDEHYDE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 3-Phenanthrenecarbaldehyde

There total 12 articles about 3-Phenanthrenecarbaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

3-(bromomethyl)phenanthrene (24471-44-1) → phenanthrene-3-carbaldehyde (7466-50-4)

Guidance literature:

With 2-nitropropane; sodium methylate; In methanol; at 22 ℃; for 14h;

Reference yield: 71.0%

phenantrene-3-carboxylic acid chloride (96403-16-6) → phenanthrene-3-carbaldehyde (7466-50-4)

Guidance literature:

With triphenylphosphine; In acetone; at 20 ℃; for 1h;

DOI:10.1055/s-2007-983744

Reference yield:

→ phenanthrene-3-carbaldehyde (7466-50-4)

Guidance literature:

With Pd-BaSO₄; decalin; at 180 - 185 ℃; Hydrogenation;

DOI:10.1021/ja01334a065

upstream raw materials:

phenanthrene-3-carbanilide

1-(phenanthren-3-yl)ethanone

3-(bromomethyl)phenanthrene

phenantrene-3-carboxylic acid chloride

Downstream raw materials:

trans-3-Styrylphenanthrene

<12>-helicene

3-[(Z)-2-(2-Bromo-5-fluoro-phenyl)-vinyl]-phenanthrene

[3]Phenanthryl-methanol

Refernces

• 1、 Hewlins, Michael J. E.,Salter, Rhys. "Preparation of polycyclic azaarenes by an extended Pomeranz-Fritsch procedure". . p. 2157 - 2163. Retrieved 2008/03/28.
• 2、 Bair,Andrews,Tuttle,Knick,Cory,McKee. "2-[(arylmethyl)amino]-2-methyl-1,3-propanediol DNA intercalators. An examination of the effects of aromatic ring variation on antitumor activity and DNA binding". . p. 1983 - 1990. Retrieved 2007/10/02.